UV photolysis of oxalyl chloride and 2,3-butanedione studied by time-resolved FTIR
文献类型：期刊论文
| 作者 | Li, Q; Li, HZ; Kong, F |
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 1999-03-01 |
| 卷号 | 15期号:3页码:259-264 |
| 关键词 | Oxalyl Chloride Uv Photolysis Ir Emission Spectrum 2 3-butanedione |
| ISSN号 | 1000-6818 |
| DOI | 10.3866/PKU.WHXB19990312 |
| 英文摘要 | The photodissociation of oxalyl chloride anti 2,3-butanedione at 193nm and 248nm have been studied by Time-resolved FTIR emission spectroscopy, The IR fluorescence emission was observed and the rotational and vibrational populations ai the CO product were obtained. It is suggested that the photolysis mechanism is two RCO radicals formed via a fission of C-C bond, followed by a decomposition of the RCO intermediate to vibrationally excited CO(v) and R radical. |
| 语种 | 英语 |
| WOS记录号 | WOS:000079433200012 |
| 出版者 | PEKING UNIV PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/74915]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Kong, F |
| 作者单位 | Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Q,Li, HZ,Kong, F. UV photolysis of oxalyl chloride and 2,3-butanedione studied by time-resolved FTIR[J]. ACTA PHYSICO-CHIMICA SINICA,1999,15(3):259-264. |
| APA | Li, Q,Li, HZ,&Kong, F.(1999).UV photolysis of oxalyl chloride and 2,3-butanedione studied by time-resolved FTIR.ACTA PHYSICO-CHIMICA SINICA,15(3),259-264. |
| MLA | Li, Q,et al."UV photolysis of oxalyl chloride and 2,3-butanedione studied by time-resolved FTIR".ACTA PHYSICO-CHIMICA SINICA 15.3(1999):259-264. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。