Catalytic behavior of magnesium oxide supported polytitazane-platinum complex for oxygenation of 2-octanol to 2-octanone
文献类型：期刊论文
| 作者 | Meng, ZH; Shi, R; Huang, MY; Jiang, YY |
| 刊名 | POLYMERS FOR ADVANCED TECHNOLOGIES
 |
| 出版日期 | 1999 |
| 卷号 | 10期号:1-2页码:95-98 |
| 关键词 | 2-octanol Oxygenation Polytitazane-platinum Complex |
| ISSN号 | 1042-7147 |
| 英文摘要 | Magnesium oxide supported polytitazane-platinum complex was prepared and characterized by x-ray photoelectron spectroscopy. N/Pt molar ratio, temperature and solvent greatly influenced the activity of the catalyst. The complex with Pt content of 1.75 mmol/g was the most effective catalyst for the oxygenation of 2-octanol to 2-octanone when diethyl carbonate was used as solvent. The yield of octanone can amount to 100%, with 100% selectivity within 8 hr at 100 degrees C under 1 atm O-2. The catalyst can be recycled for several times in the oxygenation reactions without appreciable loss in activity. (C) 1999 John Wiley & Sons, Ltd. |
| 语种 | 英语 |
| WOS记录号 | WOS:000078515800018 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/74975]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Meng, ZH |
| 作者单位 | Acad Sinica, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Meng, ZH,Shi, R,Huang, MY,et al. Catalytic behavior of magnesium oxide supported polytitazane-platinum complex for oxygenation of 2-octanol to 2-octanone[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,1999,10(1-2):95-98. |
| APA | Meng, ZH,Shi, R,Huang, MY,&Jiang, YY.(1999).Catalytic behavior of magnesium oxide supported polytitazane-platinum complex for oxygenation of 2-octanol to 2-octanone.POLYMERS FOR ADVANCED TECHNOLOGIES,10(1-2),95-98. |
| MLA | Meng, ZH,et al."Catalytic behavior of magnesium oxide supported polytitazane-platinum complex for oxygenation of 2-octanol to 2-octanone".POLYMERS FOR ADVANCED TECHNOLOGIES 10.1-2(1999):95-98. |
入库方式： OAI收割
来源：化学研究所
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