Selective hydrogenation of alpha,beta-unsaturated aldehyde to alpha,beta-unsaturated alcohol over polymer-stabilized platinum colloid and the promotion effect of metal cations
文献类型：期刊论文
| 作者 | Yu, WY; Liu, HF; Liu, MH; Tao, Q |
| 刊名 | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
 |
| 出版日期 | 1999-02-05 |
| 卷号 | 138期号:2-3页码:273-286 |
| 关键词 | Selective Hydrogenation Cinnamaldehyde Crotonaldehyde Pt Colloid Metal Cation |
| ISSN号 | 1381-1169 |
| 英文摘要 | The modification of some metal cations to polymer-stabilized platinum colloid leads to remarkable increases in both the activity and the selectivity in liquid-phase selective hydrogenation of cinnamaldehyde to cinnamyl alcohol and of crotonaldehyde to crotyl alcohol. The promotion effect was due to the interaction of metal cations and the C=O groups in reactants. The adsorbed metal cations activated the C=O double bonds to accelerate the reaction rate and to increase the selectivity to alpha,beta-unsaturated alcohols. The steric hindrance also played an important role in the reaction. (C) 1999 Elsevier Science B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000078114300018 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/75075]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, HF |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, WY,Liu, HF,Liu, MH,et al. Selective hydrogenation of alpha,beta-unsaturated aldehyde to alpha,beta-unsaturated alcohol over polymer-stabilized platinum colloid and the promotion effect of metal cations[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,1999,138(2-3):273-286. |
| APA | Yu, WY,Liu, HF,Liu, MH,&Tao, Q.(1999).Selective hydrogenation of alpha,beta-unsaturated aldehyde to alpha,beta-unsaturated alcohol over polymer-stabilized platinum colloid and the promotion effect of metal cations.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,138(2-3),273-286. |
| MLA | Yu, WY,et al."Selective hydrogenation of alpha,beta-unsaturated aldehyde to alpha,beta-unsaturated alcohol over polymer-stabilized platinum colloid and the promotion effect of metal cations".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 138.2-3(1999):273-286. |
入库方式： OAI收割
来源：化学研究所
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