Studies on HeI ultraviolet photoelectron spectra and electronic structure of N-(2-bromo-ethyl)carbazole and N-ethenylcarbazole
文献类型：期刊论文
| 作者 | Chen, RZ; Zheng, SJ; Ren, J; Wang, DX |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 1999 |
| 卷号 | 57期号:7页码:718-723 |
| 关键词 | n - (2-bromo - Ethyl) Carbazole n - Ethenylcarbazole Hei Ultraviolet Photoelectron Spectra(Ups) Rhf/6-31g |
| ISSN号 | 0567-7351 |
| 英文摘要 | HeI ultraviolet photoelectron spectra (UPS) of N - (2 - bromo - ethyl) carbazole and N ethenylcarbazole are recorded for the first time. Using the configuration optimized at RHF/6 - 31G level, the SCF MO calculations of the tyro compounds are carried out at RHF/6 - 31G* level. The UPS of the two compounds are assigned and the electronic structures are discussed based on the SCF MO calculations, contrasting with the ionization potentials (IPs) changing rules of carbazole and N - alkylcarbazole. The result shows that the UPS of N - (2 - bromo - ethyl) carbazole exists two lone - pair ionization bands of Br atom at 10.295, 10.540eV, which is different from that of N - alkylcarbazole. The special IPs changing rules of N - ethenylcarbazole compared with carbazole show that the molecule is almost planar. |
| 语种 | 英语 |
| WOS记录号 | WOS:000081781700012 |
| 出版者 | ACTA CHIMICA SINICA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/75079]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Chen, RZ |
| 作者单位 | 1.Hebei Normal Univ, Dept Chem, Shijiazhuang 050091, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, RZ,Zheng, SJ,Ren, J,et al. Studies on HeI ultraviolet photoelectron spectra and electronic structure of N-(2-bromo-ethyl)carbazole and N-ethenylcarbazole[J]. ACTA CHIMICA SINICA,1999,57(7):718-723. |
| APA | Chen, RZ,Zheng, SJ,Ren, J,&Wang, DX.(1999).Studies on HeI ultraviolet photoelectron spectra and electronic structure of N-(2-bromo-ethyl)carbazole and N-ethenylcarbazole.ACTA CHIMICA SINICA,57(7),718-723. |
| MLA | Chen, RZ,et al."Studies on HeI ultraviolet photoelectron spectra and electronic structure of N-(2-bromo-ethyl)carbazole and N-ethenylcarbazole".ACTA CHIMICA SINICA 57.7(1999):718-723. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。