Synthesis, properties, and application of new luminescent polymers with both hole and electron injection abilities for light-emitting devices
文献类型：期刊论文
| 作者 | Li, XC; Liu, YQ; Liu, MS; Jen, AKY |
| 刊名 | CHEMISTRY OF MATERIALS
 |
| 出版日期 | 1999-06-01 |
| 卷号 | 11期号:6页码:1568-1575 |
| ISSN号 | 0897-4756 |
| 英文摘要 | New luminescent polymers that contain both electron-withdrawing cyano groups and electron-rich moieties, triphenylamine (TPA) or tetraphenyldiaminobiphenyl (TPD), were synthesized by Knoevenagel condensation of 1,4-bis(cyanomethyl)-2-[(2-ethylhexyl)oxy]-5-methoxybenzene with the dialdehyde of TPA or TPD, respectively. The polymers were characterized by NMR, FT-IR, microanalysis, GPC, DSC, and TGA. Efficient orange photoluminescence was observed with an absolute quantum efficiency of 48% for the TPA incorporated polymer (TPA-CNPPV). Cyclic voltammetry investigation showed that the polymers presented reversible oxidation and reduction with relatively low potentials, which suggested that the polymers have both good electron and hole injection abilities. We demonstrated an effective approach to synthesize polymers with the triad properties of efficient photoluminescence, good hole injection and high electron-affinity properties, which are highly desirable for application in light-emitting devices. This point was supported by the demonstration of a single layer light-emitting device with a configuration of ITO/TPA-CNPPV/Al, in which good external quantum efficiency (0.1%) and bright luminance of 2100 cd/m(2) was achieved. Multilayer LEDs using the polymers as the active layers and different charge injection/transporting layers were also investigated. |
| 语种 | 英语 |
| WOS记录号 | WOS:000080886100025 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/75189]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jen, AKY |
| 作者单位 | 1.Northeastern Univ, Dept Chem, Boston, MA 02115 USA 2.Acad Sinica, Inst Chem, Beijin, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, XC,Liu, YQ,Liu, MS,et al. Synthesis, properties, and application of new luminescent polymers with both hole and electron injection abilities for light-emitting devices[J]. CHEMISTRY OF MATERIALS,1999,11(6):1568-1575. |
| APA | Li, XC,Liu, YQ,Liu, MS,&Jen, AKY.(1999).Synthesis, properties, and application of new luminescent polymers with both hole and electron injection abilities for light-emitting devices.CHEMISTRY OF MATERIALS,11(6),1568-1575. |
| MLA | Li, XC,et al."Synthesis, properties, and application of new luminescent polymers with both hole and electron injection abilities for light-emitting devices".CHEMISTRY OF MATERIALS 11.6(1999):1568-1575. |
入库方式： OAI收割
来源：化学研究所
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