Synthesis and characterization of reactive ladderlike polyallylsilsesquioxane and polyvinylsilsesquioxane
文献类型：期刊论文
| 作者 | Li, Z; Cao, XY; Xu, H; Xie, P; Cao, M; Zhang, RB |
| 刊名 | REACTIVE & FUNCTIONAL POLYMERS
 |
| 出版日期 | 1999-01-15 |
| 卷号 | 39期号:1页码:1-7 |
| 关键词 | Ladderlike Polysilsesquioxane Stepwise Coupling Polymerization |
| ISSN号 | 1381-5148 |
| 英文摘要 | Ordered reactive ladderlike polyallylsilsesquioxane (hereafter referred to as Allyl-T) and polyvinylsilsesquioxane (hereaftef VI-T) were synthesized via stepwise coupling polymerization. During this reaction, coupling agent p-phenyl enediamine (PDA) is supposed to act as a template which enables silane molecules to self-assemble through strong hydrogen-bonding interaction between SI-OH groups and N-H groups. The structure of the polymers was characterized by IR, X-ray diffraction, DSC, GPC, H-1-NMR, C-13-NMR and Si-29-NMR. The data show that the two polymers have ordered ladderlike molecular structure. Hence, the stepwise coupling polymerization is suitable to synthesize ladderlike polysilsesquioxanes (LPSs) containing grafted reactive vinyl-terminated groups. (C) 1999 Elsevier Science B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000077720300001 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/75205]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, RB |
| 作者单位 | 1.Chinese Acad Sci, Polymer Chem Lab, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Chem, China Petrochem Corp, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Z,Cao, XY,Xu, H,et al. Synthesis and characterization of reactive ladderlike polyallylsilsesquioxane and polyvinylsilsesquioxane[J]. REACTIVE & FUNCTIONAL POLYMERS,1999,39(1):1-7. |
| APA | Li, Z,Cao, XY,Xu, H,Xie, P,Cao, M,&Zhang, RB.(1999).Synthesis and characterization of reactive ladderlike polyallylsilsesquioxane and polyvinylsilsesquioxane.REACTIVE & FUNCTIONAL POLYMERS,39(1),1-7. |
| MLA | Li, Z,et al."Synthesis and characterization of reactive ladderlike polyallylsilsesquioxane and polyvinylsilsesquioxane".REACTIVE & FUNCTIONAL POLYMERS 39.1(1999):1-7. |
入库方式： OAI收割
来源：化学研究所
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