Synthesis and crystal structure of [EDA][Ni(dmit)(2)](3)
文献类型:期刊论文
作者 | Sun, SQ; Wu, PJ; Zhu, DB; Xu, XY |
刊名 | CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
![]() |
出版日期 | 1999 |
卷号 | 18期号:2页码:79-83 |
关键词 | Electrocrystallization Crystal Structure Charge Transfer Salt |
ISSN号 | 0254-5861 |
英文摘要 | The crystal structure of the compound [EDA] [Ni(dmit)(2)](3) (EDA = 2-diethylamino-1,3-dithioanylium; dmit = 1,3-dithiole-2-thione-4,5-dithiolate) C25H14NNi3S32, has been determined by single crystal X-ray diffraction at 300K. The crystal is triclinic with space group P (1) over bar, a = 11. 252, b = 12.192(2), c = 20.055(6) Angstrom, alpha = 108.127(2), beta = 106.281(8), gamma = 90.005(9)degrees; V = 2498.3(3) Angstrom(3), Z = 2, M-r = 1530.38, D-c = 2.03(2) g/cm(3). Final R and R-w values were 0.0603 and 0.0104, respectively. The structure consists of thick layers of stacked Ni(dmit)(2) entities separated by EDA cations. This salt shows semiconducting behaviour with room temperature conductivity of 0.2 Scm(-1) and activation energy of 0.11 eV. |
语种 | 英语 |
WOS记录号 | WOS:000079407200001 |
出版者 | CHINESE JOURNAL STRUCTURAL CHEMISTRY |
源URL | [http://ir.iccas.ac.cn/handle/121111/75243] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Sun, SQ |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 2.Capital Univ Med Sci, Basic Sch Med Sci, Beijing 100054, Peoples R China |
推荐引用方式 GB/T 7714 | Sun, SQ,Wu, PJ,Zhu, DB,et al. Synthesis and crystal structure of [EDA][Ni(dmit)(2)](3)[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,1999,18(2):79-83. |
APA | Sun, SQ,Wu, PJ,Zhu, DB,&Xu, XY.(1999).Synthesis and crystal structure of [EDA][Ni(dmit)(2)](3).CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,18(2),79-83. |
MLA | Sun, SQ,et al."Synthesis and crystal structure of [EDA][Ni(dmit)(2)](3)".CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 18.2(1999):79-83. |
入库方式: OAI收割
来源:化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。