中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis and crystal structure of [EDA][Ni(dmit)(2)](3)

文献类型:期刊论文

作者Sun, SQ; Wu, PJ; Zhu, DB; Xu, XY
刊名CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
出版日期1999
卷号18期号:2页码:79-83
关键词Electrocrystallization Crystal Structure Charge Transfer Salt
ISSN号0254-5861
英文摘要The crystal structure of the compound [EDA] [Ni(dmit)(2)](3) (EDA = 2-diethylamino-1,3-dithioanylium; dmit = 1,3-dithiole-2-thione-4,5-dithiolate) C25H14NNi3S32, has been determined by single crystal X-ray diffraction at 300K. The crystal is triclinic with space group P (1) over bar, a = 11. 252, b = 12.192(2), c = 20.055(6) Angstrom, alpha = 108.127(2), beta = 106.281(8), gamma = 90.005(9)degrees; V = 2498.3(3) Angstrom(3), Z = 2, M-r = 1530.38, D-c = 2.03(2) g/cm(3). Final R and R-w values were 0.0603 and 0.0104, respectively. The structure consists of thick layers of stacked Ni(dmit)(2) entities separated by EDA cations. This salt shows semiconducting behaviour with room temperature conductivity of 0.2 Scm(-1) and activation energy of 0.11 eV.
语种英语
WOS记录号WOS:000079407200001
出版者CHINESE JOURNAL STRUCTURAL CHEMISTRY
源URL[http://ir.iccas.ac.cn/handle/121111/75243]  
专题中国科学院化学研究所
通讯作者Sun, SQ
作者单位1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
2.Capital Univ Med Sci, Basic Sch Med Sci, Beijing 100054, Peoples R China
推荐引用方式
GB/T 7714
Sun, SQ,Wu, PJ,Zhu, DB,et al. Synthesis and crystal structure of [EDA][Ni(dmit)(2)](3)[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,1999,18(2):79-83.
APA Sun, SQ,Wu, PJ,Zhu, DB,&Xu, XY.(1999).Synthesis and crystal structure of [EDA][Ni(dmit)(2)](3).CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,18(2),79-83.
MLA Sun, SQ,et al."Synthesis and crystal structure of [EDA][Ni(dmit)(2)](3)".CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 18.2(1999):79-83.

入库方式: OAI收割

来源:化学研究所

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