中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Effects of nitrogen on the carbon anode of a lithium secondary battery

文献类型:期刊论文

作者Wu, YP; Fang, SB; Jiang, YY
刊名SOLID STATE IONICS
出版日期1999-05-01
卷号120期号:1-4页码:117-123
关键词Carbon Anode Nitrogen Effect Lithium Secondary Battery
ISSN号0167-2738
英文摘要Nitrogen-containing carbons have been made from different polymer precursors at 600 degrees C. Their composition and structure have been studied by chemical analysis, X-ray powder diffraction and X-ray photoelectron spectroscopy. These results show that this kind of carbon is disordered, and nitrogen exists as two kinds of forms in the polymeric carbons: graphene nitrogen (N-1s binding energy 398.5 eV) and conjugated nitrogen (N-1s binding energy 400.2 eV). The discharge and charge process suggests that these two kinds of nitrogen are bonded satisfactorily and could not result in irreversible reaction with Li. The increase of reversible capacity mainly results from the graphene nitrogen, and the higher the content of nitrogen, the higher the charge capacity. Part of the irreversible capacity is derived from the formed lithium carbide and lithium atoms which are intercalated and could not be deintercalated. (C) 1999 Elsevier Science B.V. All rights reserved.
语种英语
WOS记录号WOS:000080091800014
出版者ELSEVIER SCIENCE BV
源URL[http://ir.iccas.ac.cn/handle/121111/75311]  
专题中国科学院化学研究所
通讯作者Wu, YP
作者单位Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Wu, YP,Fang, SB,Jiang, YY. Effects of nitrogen on the carbon anode of a lithium secondary battery[J]. SOLID STATE IONICS,1999,120(1-4):117-123.
APA Wu, YP,Fang, SB,&Jiang, YY.(1999).Effects of nitrogen on the carbon anode of a lithium secondary battery.SOLID STATE IONICS,120(1-4),117-123.
MLA Wu, YP,et al."Effects of nitrogen on the carbon anode of a lithium secondary battery".SOLID STATE IONICS 120.1-4(1999):117-123.

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来源:化学研究所

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