Methanol synthesis from syngas in the homogeneous system
文献类型：期刊论文
| 作者 | Li, KL; Jiang, DZ |
| 刊名 | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
 |
| 出版日期 | 1999-11-17 |
| 卷号 | 147期号:1-2页码:125-130 |
| 关键词 | Methanol Homogeneous Synthesis Nickel Catalyst Low Temperature Additives |
| ISSN号 | 1381-1169 |
| 英文摘要 | Homogeneous synthesis of methanol from synthetic gas was carried out in the Ni(CO)(4)/KOMe catalytic system. The influence of various factors, such as the reaction temperature, the concentration of potassium methoxide, the concentration of nickel tetracarbonyl and the reaction pressure on the catalytic activity, was discussed, respectively, and the most preferred conditions were obtained. The results showed that methanol could be prepared from carbon monoxide and hydrogen under mild reaction conditions. The catalytic reactions were operated most preferably at 378 K and 1.8 MPa. The activity of catalyst characterized by space-time yield (STY) is about 4 mol/1 h. The effect of additives containing N-, O-, S-elements on the catalytic activity was also investigated. (C) 1999 Elsevier Science B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000083978400018 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/75323]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jiang, DZ |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, KL,Jiang, DZ. Methanol synthesis from syngas in the homogeneous system[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,1999,147(1-2):125-130. |
| APA | Li, KL,&Jiang, DZ.(1999).Methanol synthesis from syngas in the homogeneous system.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,147(1-2),125-130. |
| MLA | Li, KL,et al."Methanol synthesis from syngas in the homogeneous system".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 147.1-2(1999):125-130. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。