Morphological evolution with phase inversion process in emulsifying epoxy resin
文献类型：期刊论文
| 作者 | Yang, ZZ; Zhao, DL; Xu, YZ; Xu, M |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 1999-05-01 |
| 卷号 | 20期号:5页码:809-813 |
| 关键词 | Bisphenol a Epoxy Resin Phase Inversion Sem Morphological Evolution Waterborne Polymer Particles |
| ISSN号 | 0251-0790 |
| 英文摘要 | The morphological evolution with phase inversion process in emulsifying bisphenol A epoxy resin was observed by SEM. It is revealed that the phase inversion process is completely achieved at the phase inversion point(PIP) when the concentration of the emulsifier is high, and a kind of sub-micro waterborne particles of narrow size distribution is prepared, When the concentration of the emulsifier is low, the phase inversion process is incompletely achieved at PIP, and a kind of porous complex big waterborne particles of wide size distribution is obtained. In the former case, the interfacial layer of W/O structure is strong enough to impede the coalescence among water droplets before PIP. When the content of water reaches a critical value, the attraction between water droplets exceeds the repulsion, the nearest water droplets coalesce simultaneously to be continuous phase, which causes the complete phase inversion. In the latter case, the coalescence among the water droplets is noticeable due to the weak interfacial layer of W/O structure, Thus, the water droplets become larger after the coalescence and randomly dispersed in the continuous phase, The larger water drops coalesce furtherly to be continuous phase promoted by strong shear field and the W/O/W structure is formed. This is the feature of incomplete phase inversion. |
| 语种 | 英语 |
| WOS记录号 | WOS:000080428600034 |
| 出版者 | HIGHER EDUCATION PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/75339]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yang, ZZ |
| 作者单位 | Chinese Acad Sci, Inst Chem, Polymer Phys Lab, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, ZZ,Zhao, DL,Xu, YZ,et al. Morphological evolution with phase inversion process in emulsifying epoxy resin[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,1999,20(5):809-813. |
| APA | Yang, ZZ,Zhao, DL,Xu, YZ,&Xu, M.(1999).Morphological evolution with phase inversion process in emulsifying epoxy resin.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,20(5),809-813. |
| MLA | Yang, ZZ,et al."Morphological evolution with phase inversion process in emulsifying epoxy resin".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 20.5(1999):809-813. |
入库方式： OAI收割
来源：化学研究所
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