Improvement on stability of square planar rhodium (I) complexes for carbonylation of methanol to acetic acid
文献类型：期刊论文
| 作者 | Jiang, H; Pan, PL; Yuan, GQ; Chen, XZ |
| 刊名 | SCIENCE IN CHINA SERIES B-CHEMISTRY
 |
| 出版日期 | 1999-06-01 |
| 卷号 | 42期号:3页码:311-315 |
| 关键词 | Rhodium Complex Square Planar Intramolecular Substitution |
| ISSN号 | 1006-9291 |
| 英文摘要 | A series of square planar cis-dicarbonyl polymer coordinated rhodium complexes with uncoordinated donors near the central rhodium atoms for carbonylation of methanol to acetic acid are reported. Data of IR, XPS and thermal analysis show that these complexes are very stable. The intramolecular substitution reaction is proposed for their high stability. These complexes show excellent catalytic activity, selectivity and less erosion to the equipment for the methanol carbonylation to acetic acid. The distillation process may be used instead of flash vaporization in the manufacture of acetic acid, which reduces the investment on the equipment. |
| 语种 | 英语 |
| WOS记录号 | WOS:000080893100012 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/75371]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yuan, GQ |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 2.Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, H,Pan, PL,Yuan, GQ,et al. Improvement on stability of square planar rhodium (I) complexes for carbonylation of methanol to acetic acid[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,1999,42(3):311-315. |
| APA | Jiang, H,Pan, PL,Yuan, GQ,&Chen, XZ.(1999).Improvement on stability of square planar rhodium (I) complexes for carbonylation of methanol to acetic acid.SCIENCE IN CHINA SERIES B-CHEMISTRY,42(3),311-315. |
| MLA | Jiang, H,et al."Improvement on stability of square planar rhodium (I) complexes for carbonylation of methanol to acetic acid".SCIENCE IN CHINA SERIES B-CHEMISTRY 42.3(1999):311-315. |
入库方式： OAI收割
来源：化学研究所
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