Dynamic and static properties of polyoxymethylene chains
文献类型：期刊论文
| 作者 | Zhang, LX; Xia, A; Zhao, DL |
| 刊名 | EUROPEAN POLYMER JOURNAL
 |
| 出版日期 | 1999-10-01 |
| 卷号 | 35期号:10页码:1911-1917 |
| 关键词 | Monte Carlo Simulation Relaxation Time Bond-fluctuation Model Static Properties |
| ISSN号 | 0014-3057 |
| 英文摘要 | The dynamics and conformational-dependent properties of polyoxymethylene (POM) chains are studied using the modified bond-fluctuation model and the rotational-isomeric state model. In our bond-fluctuation model, a Kuhnian bond includes four carbon-oxygen bonds. Each Kuhnian bond may have different energy, and the Kuhnian bond energy is calculated using the tetrahedral lattice model as it gives a reasonable approximation to the carbon-oxygen backbone bond of the POM chain. Our statistical mechanics properties of chains are in good agreement with the theoretical results. The relaxation times tau(1) increase with chain length N by a power law of the form tau(1)(N) approximate to N-2 in the absence of excluded volume and tau(1)(N) approximate to N-2.16 in the presence of excluded volume, and the diffusion coefficients D behave as D approximate to 1/N in the absence and presence of excluded volume. (C) 1999 Elsevier Science Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000081882900019 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/75403]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, LX |
| 作者单位 | 1.Zhejiang Univ, Dept Phys, Hangzhou 310028, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, LX,Xia, A,Zhao, DL. Dynamic and static properties of polyoxymethylene chains[J]. EUROPEAN POLYMER JOURNAL,1999,35(10):1911-1917. |
| APA | Zhang, LX,Xia, A,&Zhao, DL.(1999).Dynamic and static properties of polyoxymethylene chains.EUROPEAN POLYMER JOURNAL,35(10),1911-1917. |
| MLA | Zhang, LX,et al."Dynamic and static properties of polyoxymethylene chains".EUROPEAN POLYMER JOURNAL 35.10(1999):1911-1917. |
入库方式： OAI收割
来源：化学研究所
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