中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Effects of chain length and structure of cationic surfactants on the adsorption onto Na-Kaolinite

文献类型:期刊论文

作者Wang, JB; Han, BX; Dai, M; Yan, HK; Li, ZX; Thomas, RK
刊名JOURNAL OF COLLOID AND INTERFACE SCIENCE
出版日期1999-05-15
卷号213期号:2页码:596-601
关键词Cationic Surfactants Kaolinite Adsorption Zeta Potential Surface Tension
ISSN号0021-9797
英文摘要The adsorption of a series of alkylammonium bromides (RR1N(CH3)(2)Br) with different chain lengths R and R-1 on a nonswelling clay surface (sodium kaolinite) has been studied by microelectrophoresis and adsorption isotherms. An increase in the number of CH2 groups in the shorter alkyl chain of the double-chain surfactant, or the introduction of another kind of alkyl group (phenyl group), was found to have much less effect on the adsorption behavior than changing the length of the alkyl chain in the single-chain surfactants. It is inferred that the effective hydrophobicity of the shorter chains in these double-chain surfactants is reduced by their intramolecular association with the longer chain. Comparison of adsorption and micellization leads to an empirical quantitative description of the effects of alkyl chain length and structure on adsorption. (C) 1999 Academic Press.
语种英语
WOS记录号WOS:000080117500036
出版者ACADEMIC PRESS INC
源URL[http://ir.iccas.ac.cn/handle/121111/75405]  
专题中国科学院化学研究所
通讯作者Yan, HK
作者单位1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
2.Univ Oxford, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England
推荐引用方式
GB/T 7714
Wang, JB,Han, BX,Dai, M,et al. Effects of chain length and structure of cationic surfactants on the adsorption onto Na-Kaolinite[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,1999,213(2):596-601.
APA Wang, JB,Han, BX,Dai, M,Yan, HK,Li, ZX,&Thomas, RK.(1999).Effects of chain length and structure of cationic surfactants on the adsorption onto Na-Kaolinite.JOURNAL OF COLLOID AND INTERFACE SCIENCE,213(2),596-601.
MLA Wang, JB,et al."Effects of chain length and structure of cationic surfactants on the adsorption onto Na-Kaolinite".JOURNAL OF COLLOID AND INTERFACE SCIENCE 213.2(1999):596-601.

入库方式: OAI收割

来源:化学研究所

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