Effects of nucleating agent and nucleation promoter on the crystallization of polyethylene terephthalate
文献类型:期刊论文
作者 | Chen, Y; Xu, M; Li, YY; He, JS |
刊名 | ACTA POLYMERICA SINICA
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出版日期 | 1999-02-01 |
期号 | 1页码:7-14 |
关键词 | Nucleating Agent Nucleation Promoter Pet |
ISSN号 | 1000-3304 |
英文摘要 | The influence of a nucleating agent, a nucleation promoter and their mixture on the crystallization of poly(ethylene terephthalate) (PET) from melt state was studied by different characterization techniques including the measurements of the crystallization temperature in a non-isothermal cooling process, half time in an isothermal crystallization process and the specific surface free energy for nucleus formation during crystallization. The nucleating agent used was a derivative of sodium benzoate while the nucleation promoter was a sort of low molecular weight ester-ether copolymer. It was found that the nucleating agent could promote the nucleation and crystallization of PET, reducing the specific surface free energy for nucleus formation during crystallization. However, the nucleation promoter had little influence on the nucleation and crystallization rate of PET in the high crystallization temperature range. The nucleation promoter may slightly increase the degree of crystallinity of PET, when the mixture of the nucleating agent and the nucleation promoter was used, the crystallization behavior of PET from its melt state was mainly controlled by the nucleating agent. |
语种 | 英语 |
WOS记录号 | WOS:000078636200002 |
出版者 | SCIENCE PRESS |
源URL | [http://ir.iccas.ac.cn/handle/121111/75413] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Chen, Y |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Polymer Phys Lab, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Chem, State Key Lab Engn Plast, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Y,Xu, M,Li, YY,et al. Effects of nucleating agent and nucleation promoter on the crystallization of polyethylene terephthalate[J]. ACTA POLYMERICA SINICA,1999(1):7-14. |
APA | Chen, Y,Xu, M,Li, YY,&He, JS.(1999).Effects of nucleating agent and nucleation promoter on the crystallization of polyethylene terephthalate.ACTA POLYMERICA SINICA(1),7-14. |
MLA | Chen, Y,et al."Effects of nucleating agent and nucleation promoter on the crystallization of polyethylene terephthalate".ACTA POLYMERICA SINICA .1(1999):7-14. |
入库方式: OAI收割
来源:化学研究所
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