In situ doping polymerization of polyaniline microtubules in the presence of beta-naphthalenesulfonic acid
文献类型：期刊论文
| 作者 | Huang, J; Wan, MX |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
 |
| 出版日期 | 1999-01-15 |
| 卷号 | 37期号:2页码:151-157 |
| 关键词 | Conducting Microtubules Polyaniline (Pani) Beta-naphthalenesulfonic Acid (Nsa) In Situ dopIng Polymerization |
| ISSN号 | 0887-624X |
| 英文摘要 | Conducting microtubules of Polyaniline (PANI) were synthesized for the first time by the "in situ doping polymerization" method in the presence of p-naphthalenesulfonic acid (NSA) as dopant. Different doping methods, such as "immerse doping'' and "grind doping," and different synthetic conditions, such as molar ratio of aniline (An) to NSA (An/NSA), concentration of NSA in the polymerization media, reaction temperature, and time were investigated to understand the formation of microtubules. it was found that the PANI-NSA microtubules can be formed only by the "in situ doping polymerization" method, and the above synthetic conditions strongly affect the formation of the PANE-NSA microtubules, especially the molar ratio of An to NSA. An optimal condition was found under which tubules with 1-3 mu m in diameter and 10-50 mu m in length were obtained. The morphology of PANI-NSA tubules was proved by SEM and TEM, and their backbone structure was characterized by FTIR, W-VIS, XPS, and X-ray diffraction. Results of these measurements showed that the molecular structures of the resulted PANI-NSA microtubules were identical to that of PANI-HCl synthesized by conventional method. (C) 1999 John Wiley & Sons, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000077877400005 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/75449]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wan, MX |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, J,Wan, MX. In situ doping polymerization of polyaniline microtubules in the presence of beta-naphthalenesulfonic acid[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,1999,37(2):151-157. |
| APA | Huang, J,&Wan, MX.(1999).In situ doping polymerization of polyaniline microtubules in the presence of beta-naphthalenesulfonic acid.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,37(2),151-157. |
| MLA | Huang, J,et al."In situ doping polymerization of polyaniline microtubules in the presence of beta-naphthalenesulfonic acid".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 37.2(1999):151-157. |
入库方式： OAI收割
来源：化学研究所
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