Synthesis and properties of aniline and o-aminobenzenesulfonic acid copolymer
文献类型：期刊论文
| 作者 | Fan, JH; Wan, MX; Zhu, DB |
| 刊名 | CHINESE JOURNAL OF POLYMER SCIENCE
 |
| 出版日期 | 1999 |
| 卷号 | 17期号:2页码:165-170 |
| 关键词 | Watersoluble Polyaniline Reactivity Ratio Copolymer |
| ISSN号 | 0256-7679 |
| 英文摘要 | Poly(aniline-co-o-aminobenzenesulfonic acid) (PAOABSA) as a water soluble conducting polymer was synthesized by chemical polymerization. The productivity and the room-temperature conductivity of the copolymer were measured as a function of the reaction conditions, such as reaction temperature, the ratio of oxidant to monomer and the degree of sulfonation defined as the ratio of sulfur to nitrogen atoms(S/N). The main results obtained are summarized as follows: (1) lower reaction temperature (at about 0 degrees C) is favorable for the enhancement of the room-temperature conductivity of the copolymer; (2) higher content of oxidant is unfavorable for increasing the room-temperature conductivity of the copolymer; (3) both productivity and room-temperature conductivity of the copolymer decrease with increase of the degree of sulfonation which was always lower than 0.5 even an excess of o-aminobenzenesulfonic acid was added, probably because the reactivity ratio of aniline (gamma(1)=2.99 +/- 0.05) is much higher than that of o-aminobenzenesulfonic acid (gamma(2) = 0.06 +/- 0.02) estimated by using Fineman-Ross method and least square method. |
| 语种 | 英语 |
| WOS记录号 | WOS:000080390800010 |
| 出版者 | SPRINGER-VERLAG SINGAPORE PTE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/75453]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wan, MX |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fan, JH,Wan, MX,Zhu, DB. Synthesis and properties of aniline and o-aminobenzenesulfonic acid copolymer[J]. CHINESE JOURNAL OF POLYMER SCIENCE,1999,17(2):165-170. |
| APA | Fan, JH,Wan, MX,&Zhu, DB.(1999).Synthesis and properties of aniline and o-aminobenzenesulfonic acid copolymer.CHINESE JOURNAL OF POLYMER SCIENCE,17(2),165-170. |
| MLA | Fan, JH,et al."Synthesis and properties of aniline and o-aminobenzenesulfonic acid copolymer".CHINESE JOURNAL OF POLYMER SCIENCE 17.2(1999):165-170. |
入库方式： OAI收割
来源：化学研究所
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