Preparation and properties of (BEDT-TTF)(2)Br(center dot)3H(2)O salt
文献类型:期刊论文
作者 | Zhang, QC; Wu, PJ; Jiang, KJ; Ding, RS; Wang, YQ; Zhu, DB |
刊名 | CHINESE CHEMICAL LETTERS
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出版日期 | 1999-02-01 |
卷号 | 10期号:2页码:179-182 |
关键词 | Organic Conductor Charge Transfer Complex Preparation Electrical Properties Structure |
ISSN号 | 1001-8417 |
英文摘要 | Electrochemical oxidation of BEDT-TTF (bis (ethylenedithio) tetrathiafulvalene) in chloroform/carbon disulfide (3:1) in the presence of Bu4NBr as a supporting electrolyte at low current density results in the (BEDT-TTF)(2)Br3H(2)O crystal. Its composition has been established by chemical analysis (Br, C, H. S), XPS and IR. The temperature dependence of the resistance has been studied down to 26K at ambient pressure. This material has weakly metallic behavior above 230K, and becomes a semiconductor below this temperature. The structure of the complex is also described. |
语种 | 英语 |
WOS记录号 | WOS:000081029500033 |
出版者 | CHINESE CHEMICAL SOCIETY |
源URL | [http://ir.iccas.ac.cn/handle/121111/75473] ![]() |
专题 | 中国科学院化学研究所 |
作者单位 | Chinese Acad Sci, Inst Chem, Organ Solid Lab, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, QC,Wu, PJ,Jiang, KJ,et al. Preparation and properties of (BEDT-TTF)(2)Br(center dot)3H(2)O salt[J]. CHINESE CHEMICAL LETTERS,1999,10(2):179-182. |
APA | Zhang, QC,Wu, PJ,Jiang, KJ,Ding, RS,Wang, YQ,&Zhu, DB.(1999).Preparation and properties of (BEDT-TTF)(2)Br(center dot)3H(2)O salt.CHINESE CHEMICAL LETTERS,10(2),179-182. |
MLA | Zhang, QC,et al."Preparation and properties of (BEDT-TTF)(2)Br(center dot)3H(2)O salt".CHINESE CHEMICAL LETTERS 10.2(1999):179-182. |
入库方式: OAI收割
来源:化学研究所
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