Influence of intramolecular substitution reaction of square planar carbonyl rhodium (I) cationic complex on its stability
文献类型：期刊论文
| 作者 | Jiang, H; Pan, PL; Yuan, GQ |
| 刊名 | CHINESE SCIENCE BULLETIN
 |
| 出版日期 | 1999-07-01 |
| 卷号 | 44期号:13页码:1195-1198 |
| 关键词 | Rhodium Complex Intramolecular Substitution Stability |
| ISSN号 | 1001-6538 |
| 英文摘要 | Two cis-dicarbonyl rhodium complexes containing uncoordinated donors have been synthesized, and their IR and XPS data and the influence of their intramolecular substitution reaction on their stabilities have been reported. The intramolecular substitution reaction is reversible. Under the condition of heating and without the protection of CO, the uncoordinated donors substitute the terminal carbonyls on the rhodium to form tetradentated complex. So the rhodium complex will not decompose for the drop of the terminal carbonyls and its stability is enhanced. In atmosphere of CO, it recovers to bidentate complex. |
| 语种 | 英语 |
| WOS记录号 | WOS:000082955000009 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/75485]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yuan, GQ |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, H,Pan, PL,Yuan, GQ. Influence of intramolecular substitution reaction of square planar carbonyl rhodium (I) cationic complex on its stability[J]. CHINESE SCIENCE BULLETIN,1999,44(13):1195-1198. |
| APA | Jiang, H,Pan, PL,&Yuan, GQ.(1999).Influence of intramolecular substitution reaction of square planar carbonyl rhodium (I) cationic complex on its stability.CHINESE SCIENCE BULLETIN,44(13),1195-1198. |
| MLA | Jiang, H,et al."Influence of intramolecular substitution reaction of square planar carbonyl rhodium (I) cationic complex on its stability".CHINESE SCIENCE BULLETIN 44.13(1999):1195-1198. |
入库方式： OAI收割
来源：化学研究所
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