Anodic electrocrystallization of BaKPbO and BaKPbBiO from molten salt
文献类型：期刊论文
| 作者 | Zhang, L; Zhao, LZ; Zhang, JB; Xu, CY; Liu, SH |
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 1999-11-01 |
| 卷号 | 15期号:11页码:1049-1052 |
| 关键词 | Complex Oxides Anodic Electrocrystallization Superconductivity Electronic Structure |
| ISSN号 | 1000-6818 |
| DOI | 10.3866/PKU.WHXB19991118 |
| 英文摘要 | BaKPbO and BaKPbBiO single crystals were electrodeposited on anode by the molten salt electrochemical method using KOH/KNO3 as flux. It is found that the K content decreases when the KNO3 concentration in the flux increases. On the other hand, when the KNO3 concentration in the flux is constant, the K content increases as the Bi content in the BaKPbBiO crystals increases, The magnetic susecptibility measurements show that Ba-K-Pb-Bi-O crystals are super-conducting while BaKPbO crystals are not. XPS analyses reveal that the M(M = Pb, Bi) 6 s - O2p valence band moves toward the Fermi level when the Bi content in BaKPbBiO decreases. |
| 语种 | 英语 |
| WOS记录号 | WOS:000083915100018 |
| 出版者 | PEKING UNIV PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/75489]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, L |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, L,Zhao, LZ,Zhang, JB,et al. Anodic electrocrystallization of BaKPbO and BaKPbBiO from molten salt[J]. ACTA PHYSICO-CHIMICA SINICA,1999,15(11):1049-1052. |
| APA | Zhang, L,Zhao, LZ,Zhang, JB,Xu, CY,&Liu, SH.(1999).Anodic electrocrystallization of BaKPbO and BaKPbBiO from molten salt.ACTA PHYSICO-CHIMICA SINICA,15(11),1049-1052. |
| MLA | Zhang, L,et al."Anodic electrocrystallization of BaKPbO and BaKPbBiO from molten salt".ACTA PHYSICO-CHIMICA SINICA 15.11(1999):1049-1052. |
入库方式： OAI收割
来源：化学研究所
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