The study of intramolecular substitution reaction of polymer complex of cationic rhodium coordinated with polyallylmerrcaptan methynolacrylate
文献类型：期刊论文
| 作者 | Diao, KS; Shi, XL; Pan, PL; Yuan, GQ; Zhang, JC |
| 刊名 | ACTA POLYMERICA SINICA
 |
| 出版日期 | 2000-12-01 |
| 期号 | 6页码:711-714 |
| 关键词 | Complex Square Planar Intramolecular Substitution |
| ISSN号 | 1000-3304 |
| 英文摘要 | A new kind of cis-dicarbonyl rhodium complex,which contained S and O atoms as uncoordinated donors,has been synthesized. After studying its intramolecular substitution reaction through IR and XPS data,the result indicated that the weak S-->Rh and the weaker O-->Rh coordination bonds can replace the strong Rh-CR back donation bond to form tetradentated complex with the elevation of temperature and without the protection of CO. So the rhodium complex will not decompose for the drop of the terminal carbonyls and its stability is enhanced. The intramolecular substitution reaction is reversible. In the atmosphere of CO,the tetradentated complex will recover to bidentate complex with cis-dicarbonyl. |
| 语种 | 英语 |
| WOS记录号 | WOS:000165910900011 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/75631]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Diao, KS |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 2.Beijing Univ Chem Technol, Dept Appl Chem, Beijing 100029, Peoples R China |
| 推荐引用方式 GB/T 7714 | Diao, KS,Shi, XL,Pan, PL,et al. The study of intramolecular substitution reaction of polymer complex of cationic rhodium coordinated with polyallylmerrcaptan methynolacrylate[J]. ACTA POLYMERICA SINICA,2000(6):711-714. |
| APA | Diao, KS,Shi, XL,Pan, PL,Yuan, GQ,&Zhang, JC.(2000).The study of intramolecular substitution reaction of polymer complex of cationic rhodium coordinated with polyallylmerrcaptan methynolacrylate.ACTA POLYMERICA SINICA(6),711-714. |
| MLA | Diao, KS,et al."The study of intramolecular substitution reaction of polymer complex of cationic rhodium coordinated with polyallylmerrcaptan methynolacrylate".ACTA POLYMERICA SINICA .6(2000):711-714. |
入库方式： OAI收割
来源：化学研究所
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