Synthesis and characterization of a novel terephthalate-bridged ladderlike polymethylsiloxane
文献类型：期刊论文
| 作者 | Liu, CQ; Liu, ZH; Liu, Y; Xie, P; Zhang, RB |
| 刊名 | POLYMER INTERNATIONAL
 |
| 出版日期 | 2000-12-01 |
| 卷号 | 49期号:12页码:1658-1664 |
| 关键词 | Terephthalate-bridged Ladderlike Polymethylsiloxane Stepwise Coupling Polymerization Hydrosilylation Characterization |
| ISSN号 | 0959-8103 |
| 英文摘要 | A novel soluble terephthalate-bridged ladderlike polymethylsiloxane was synthesized successfully by stepwise coupling polymerization in three steps, including hydrosilylation coupling, hydrolysis and polycondensation. The bis(3-methyldichlorosilylpropyl) terephthalate monomer was first synthesized by hydrosilylation reaction in the presence of dicyclopentadienylplatinum (II) chloride (Cp2PtCl2) catalyst. The structures of the monomer and the polymer were characterized by FTIR, H-1 NMR, C-13 NMR and Si-29 NMR spectroscopy, mass spectrometry, X-ray diffraction, differential scanning calorimetry, vapour pressure osmometry and gel permeation chromatography. Characterization data indicate that the synthesized polymer possesses an ordered ladderlike structure. (C) 2000 Society of Chemical Industry. |
| 语种 | 英语 |
| WOS记录号 | WOS:000165853700018 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/75667]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, RB |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem,China Petro Chem Corp, Ctr Mol Sci, Polymer Chem Lab, Beijing 100080, Peoples R China 2.Chinese Acad Sci, PCLCC Polymer Chem Lab, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, CQ,Liu, ZH,Liu, Y,et al. Synthesis and characterization of a novel terephthalate-bridged ladderlike polymethylsiloxane[J]. POLYMER INTERNATIONAL,2000,49(12):1658-1664. |
| APA | Liu, CQ,Liu, ZH,Liu, Y,Xie, P,&Zhang, RB.(2000).Synthesis and characterization of a novel terephthalate-bridged ladderlike polymethylsiloxane.POLYMER INTERNATIONAL,49(12),1658-1664. |
| MLA | Liu, CQ,et al."Synthesis and characterization of a novel terephthalate-bridged ladderlike polymethylsiloxane".POLYMER INTERNATIONAL 49.12(2000):1658-1664. |
入库方式： OAI收割
来源：化学研究所
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