Catalytic behaviors of silica-supported natural biopolymer-oxalic acid-Pt complexes in hydrogenation
文献类型：期刊论文
| 作者 | Liu, HW; Li, DY; Huang, MY; Jiang, YY |
| 刊名 | POLYMERS FOR ADVANCED TECHNOLOGIES
 |
| 出版日期 | 2000-05-01 |
| 卷号 | 11期号:5页码:258-261 |
| 关键词 | Biopolymer Oxalic Acid Pt Complex Catalyst Hydrogenation Nitrobenzene |
| ISSN号 | 1042-7147 |
| 英文摘要 | Three kinds of natural biopolymers, gelatin, alginic acid and sodium carboxymethylcellulose (NaCMC), were reacted with oxalic acid in the presence of silica to yield complexes on the surface of silica, followed by reaction with H2PtCl6 6H(2)O to form Pt complexes, SiO2-gelatin-(COOH)(2)-Pt, SiO2-alginic acid-(COOH)(2)-Pt, and SiO2-NaCMC-(COOH)2-Pt, respectively. These complexes were able to catalyze the hydrogenation of 1-heptene to give n-heptane and that of nitrobenzene to give aniline at 25 degrees C and under 1 atm H-2 in 100% yields. Experimental data show that the catalysts were very stable and could be reused without any remarkable change in catalytic activity. Copyright (C) 2000 John Wiley & Sons, Ltd. |
| 语种 | 英语 |
| WOS记录号 | WOS:000087653200009 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/75797]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, HW |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, HW,Li, DY,Huang, MY,et al. Catalytic behaviors of silica-supported natural biopolymer-oxalic acid-Pt complexes in hydrogenation[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2000,11(5):258-261. |
| APA | Liu, HW,Li, DY,Huang, MY,&Jiang, YY.(2000).Catalytic behaviors of silica-supported natural biopolymer-oxalic acid-Pt complexes in hydrogenation.POLYMERS FOR ADVANCED TECHNOLOGIES,11(5),258-261. |
| MLA | Liu, HW,et al."Catalytic behaviors of silica-supported natural biopolymer-oxalic acid-Pt complexes in hydrogenation".POLYMERS FOR ADVANCED TECHNOLOGIES 11.5(2000):258-261. |
入库方式： OAI收割
来源：化学研究所
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