Isothermal crystallization kinetics of PEO in poly(ethylene terephthalate)-poly(ethylene oxide) segmented copolymers. I. Effect of the sofi-block length
文献类型：期刊论文
| 作者 | Kong, XH; Tan, SS; Yang, XN; Li, G; Zhou, EL; Ma, DZ |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS
 |
| 出版日期 | 2000-12-15 |
| 卷号 | 38期号:24页码:3230-3238 |
| 关键词 | Pet-peo Segmented Copolymer Isothermal Crystallization Kinetics Avrami Equation Morphology |
| ISSN号 | 0887-6266 |
| 英文摘要 | The isothermal crystallization kinetics of poly(ethylene oxide) (PEO) block in two poly(ethylene terephthalate) (PET)-PEO segmented copolymers was studied with differential scanning calorimetry. The Avrami equation failed to describe the overall crystallization process, but a modified Avrami equation, the Q equation, did. The crystallizability of the PET block and the different lengths of the PEO block exerted strong influences on the crystallization process, the crystallinity, and time final morphology of the PEO block. The mechanism of nucleation and the growth dimension of the PEG block were different because of the crystallizability of time PET block and the compositional heterogeneity. The crystallization of the PEO block was physically constrained by the microstructure of time PET crystalline phase, which resulted in a lower crystallization rate. However, this influence became weak with the increase in the soft-block length. (C) 2000 John Wiley & Sons, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000165510900004 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/75897]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhou, EL |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Peoples R China |
| 推荐引用方式 GB/T 7714 | Kong, XH,Tan, SS,Yang, XN,et al. Isothermal crystallization kinetics of PEO in poly(ethylene terephthalate)-poly(ethylene oxide) segmented copolymers. I. Effect of the sofi-block length[J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,2000,38(24):3230-3238. |
| APA | Kong, XH,Tan, SS,Yang, XN,Li, G,Zhou, EL,&Ma, DZ.(2000).Isothermal crystallization kinetics of PEO in poly(ethylene terephthalate)-poly(ethylene oxide) segmented copolymers. I. Effect of the sofi-block length.JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,38(24),3230-3238. |
| MLA | Kong, XH,et al."Isothermal crystallization kinetics of PEO in poly(ethylene terephthalate)-poly(ethylene oxide) segmented copolymers. I. Effect of the sofi-block length".JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS 38.24(2000):3230-3238. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。