Observation of different ionic state of SiBr4 - Photoelectron spectroscopic and theoretical studies
文献类型：期刊论文
| 作者 | Sun, Z; Zheng, SJ; Wang, DX |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 2000 |
| 卷号 | 58期号:12页码:1645-1648 |
| 关键词 | Sibr4 Ionic States Photoelectron Spectroscopy(Pes) Ionization Potentials Theoretical Calculations |
| ISSN号 | 0567-7351 |
| 英文摘要 | The Photoelectron Spectroscopy(PES) and different ionic state of SiBr4 were reported in this paper. The ionic states of SiBr4+ are (XT2)-T-2, A(2)T(1), (BE)-E-2, (CT2)-T-2 respectively. The adiabatic ionization potential of the compound is I-a( X-2 T-2<-X(1)A(1)) = 10.532eV. A frequency of (450 +/- 30)cm(-1) was observed in the PES band of (XT2)-T-2 ionic state. The assignment of the PE spectrum was performed with the help of the theoretical calculations and the band characters. Obvious Spin - Orbital Coupling split was observed in (XT2)-T-2 and A(2)T(1) states, and the splitting space are 0.27eV and 0.53eV. Thee comparison of different calculations shows that the Outer Valence Green's Function (OVGF) method gives quite good results in ionization potentials calculations. |
| 语种 | 英语 |
| WOS记录号 | WOS:000166093500027 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/75933]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, Z |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 10080, Peoples R China 2.Hebei Teachers Univ, Dept Chem, Shijiazhuang 050091, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Z,Zheng, SJ,Wang, DX. Observation of different ionic state of SiBr4 - Photoelectron spectroscopic and theoretical studies[J]. ACTA CHIMICA SINICA,2000,58(12):1645-1648. |
| APA | Sun, Z,Zheng, SJ,&Wang, DX.(2000).Observation of different ionic state of SiBr4 - Photoelectron spectroscopic and theoretical studies.ACTA CHIMICA SINICA,58(12),1645-1648. |
| MLA | Sun, Z,et al."Observation of different ionic state of SiBr4 - Photoelectron spectroscopic and theoretical studies".ACTA CHIMICA SINICA 58.12(2000):1645-1648. |
入库方式： OAI收割
来源：化学研究所
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