A structural comparison study between one-dimensional organic semiconductor (BEDT-TTF)(2)HgCl3 center dot TCE and two-dimensional organic superconductor beta-(BEDT-TTF)(2)I-3
文献类型：期刊论文
| 作者 | Liu, Z; Fang, Q; Yu, WT; Liu, ZQ; Ren, Y; Jiang, MH |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 2000 |
| 卷号 | 58期号:12页码:1567-1575 |
| 关键词 | Bedt-ttf Salt Electro-crystallization Crystal Structure Conductivity |
| ISSN号 | 0567-7351 |
| 英文摘要 | A new semiconductor of organic crystal (BEDT - TTF)(2)HgCl3 . TCE, [(BEDT - TTF) = bis(ethylenedithio)tetrathiafulvalene, TCE = 1, 1, 2 - trichloroethane] has been synthesized by electro crystallization method. Its structure was determined by four - circle X - ray diffraction method. In(R/R-0) of its single crystal on be - plane was measured to have a linear relationship to T-1. In (BEDT - TTF)(2)HgCl3 . TCE crystal, the BEDT - TTF cationic radicals are arranged side - by - side equidistantly forming a kind of one - dimensional structure along the b axis. (HgCl3)(-) anions also form another kind of one - dimensional polymers (HgCl3)(n)(n-) along this direction. Therefore, (BEDT - TTF)(2)HgCl3 . TCE is an one - dimensional organic semiconductor. In order to reveal the conductivity - structure relationships, we have also synthesized the known organic superconductor beta - (BEDT - TTF)(2)I-3 and discussed why the conductivity of beta - (BEDT - TTF)(2)I-3 is Superior to that of (BEDT - TTF)(2)HgCl3 . TCE. |
| 语种 | 英语 |
| WOS记录号 | WOS:000166093500015 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/75993]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Z |
| 作者单位 | 1.Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Z,Fang, Q,Yu, WT,et al. A structural comparison study between one-dimensional organic semiconductor (BEDT-TTF)(2)HgCl3 center dot TCE and two-dimensional organic superconductor beta-(BEDT-TTF)(2)I-3[J]. ACTA CHIMICA SINICA,2000,58(12):1567-1575. |
| APA | Liu, Z,Fang, Q,Yu, WT,Liu, ZQ,Ren, Y,&Jiang, MH.(2000).A structural comparison study between one-dimensional organic semiconductor (BEDT-TTF)(2)HgCl3 center dot TCE and two-dimensional organic superconductor beta-(BEDT-TTF)(2)I-3.ACTA CHIMICA SINICA,58(12),1567-1575. |
| MLA | Liu, Z,et al."A structural comparison study between one-dimensional organic semiconductor (BEDT-TTF)(2)HgCl3 center dot TCE and two-dimensional organic superconductor beta-(BEDT-TTF)(2)I-3".ACTA CHIMICA SINICA 58.12(2000):1567-1575. |
入库方式： OAI收割
来源：化学研究所
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