中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
A structural comparison study between one-dimensional organic semiconductor (BEDT-TTF)(2)HgCl3 center dot TCE and two-dimensional organic superconductor beta-(BEDT-TTF)(2)I-3

文献类型:期刊论文

作者Liu, Z; Fang, Q; Yu, WT; Liu, ZQ; Ren, Y; Jiang, MH
刊名ACTA CHIMICA SINICA
出版日期2000
卷号58期号:12页码:1567-1575
关键词Bedt-ttf Salt Electro-crystallization Crystal Structure Conductivity
ISSN号0567-7351
英文摘要A new semiconductor of organic crystal (BEDT - TTF)(2)HgCl3 . TCE, [(BEDT - TTF) = bis(ethylenedithio)tetrathiafulvalene, TCE = 1, 1, 2 - trichloroethane] has been synthesized by electro crystallization method. Its structure was determined by four - circle X - ray diffraction method. In(R/R-0) of its single crystal on be - plane was measured to have a linear relationship to T-1. In (BEDT - TTF)(2)HgCl3 . TCE crystal, the BEDT - TTF cationic radicals are arranged side - by - side equidistantly forming a kind of one - dimensional structure along the b axis. (HgCl3)(-) anions also form another kind of one - dimensional polymers (HgCl3)(n)(n-) along this direction. Therefore, (BEDT - TTF)(2)HgCl3 . TCE is an one - dimensional organic semiconductor. In order to reveal the conductivity - structure relationships, we have also synthesized the known organic superconductor beta - (BEDT - TTF)(2)I-3 and discussed why the conductivity of beta - (BEDT - TTF)(2)I-3 is Superior to that of (BEDT - TTF)(2)HgCl3 . TCE.
语种英语
WOS记录号WOS:000166093500015
出版者SCIENCE PRESS
源URL[http://ir.iccas.ac.cn/handle/121111/75993]  
专题中国科学院化学研究所
通讯作者Liu, Z
作者单位1.Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Liu, Z,Fang, Q,Yu, WT,et al. A structural comparison study between one-dimensional organic semiconductor (BEDT-TTF)(2)HgCl3 center dot TCE and two-dimensional organic superconductor beta-(BEDT-TTF)(2)I-3[J]. ACTA CHIMICA SINICA,2000,58(12):1567-1575.
APA Liu, Z,Fang, Q,Yu, WT,Liu, ZQ,Ren, Y,&Jiang, MH.(2000).A structural comparison study between one-dimensional organic semiconductor (BEDT-TTF)(2)HgCl3 center dot TCE and two-dimensional organic superconductor beta-(BEDT-TTF)(2)I-3.ACTA CHIMICA SINICA,58(12),1567-1575.
MLA Liu, Z,et al."A structural comparison study between one-dimensional organic semiconductor (BEDT-TTF)(2)HgCl3 center dot TCE and two-dimensional organic superconductor beta-(BEDT-TTF)(2)I-3".ACTA CHIMICA SINICA 58.12(2000):1567-1575.

入库方式: OAI收割

来源:化学研究所

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