Influence of acetylation degree of cellulose acetate on pervaporation properties for MeOH/MTBE mixture
文献类型:期刊论文
作者 | Cao, SG; Shi, YQ; Chen, GW |
刊名 | JOURNAL OF MEMBRANE SCIENCE |
出版日期 | 2000-01-17 |
卷号 | 165期号:1页码:89-97 |
ISSN号 | 0376-7388 |
关键词 | Pervaporation Meoh/mtbe Mixture Acetylation Degree Cellulose Acetate Plasticization Effect |
英文摘要 | The pervaporation separation of the MeOH/MTBE mixture was performed with three cellulose acetate membranes under various feed compositions and operation temperatures. The results show that the acetylation degree has great influence on the pervaporation properties because the quantity of hydroxyl groups in the polymer matrix leads to different crystallinty degrees. The different extent of the plasticization effect resulted in membranes performing their special flux trend and selectivity over the range of feed compositions and caused the permeants to transport through the membrane in different diffusion modes under various operation temperatures. The IR sorption spectra evidenced that for membranes with different acetylation degrees there existed different sorption sites for penetrants and provided a proof for different pervaporation properties of the tested membranes. (C)2000 Elsevier Science B.V. All rights reserved. |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE BV |
WOS记录号 | WOS:000084766600008 |
源URL | [http://ir.iccas.ac.cn/handle/121111/76047] |
专题 | 中国科学院化学研究所 |
通讯作者 | Chen, GW |
作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Cao, SG,Shi, YQ,Chen, GW. Influence of acetylation degree of cellulose acetate on pervaporation properties for MeOH/MTBE mixture[J]. JOURNAL OF MEMBRANE SCIENCE,2000,165(1):89-97. |
APA | Cao, SG,Shi, YQ,&Chen, GW.(2000).Influence of acetylation degree of cellulose acetate on pervaporation properties for MeOH/MTBE mixture.JOURNAL OF MEMBRANE SCIENCE,165(1),89-97. |
MLA | Cao, SG,et al."Influence of acetylation degree of cellulose acetate on pervaporation properties for MeOH/MTBE mixture".JOURNAL OF MEMBRANE SCIENCE 165.1(2000):89-97. |
入库方式: OAI收割
来源:化学研究所
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