Asymmetric hydrogenation of salicyl alcohol catalyzed by methylsulfo-sodium carboxymethylcellulose-Pt complex
文献类型：期刊论文
| 作者 | Mao, BW; Zhao, AG; Huang, MY; Jiang, YY |
| 刊名 | POLYMERS FOR ADVANCED TECHNOLOGIES
 |
| 出版日期 | 2000-05-01 |
| 卷号 | 11期号:5页码:250-253 |
| 关键词 | Methylsulfo-sodium Carboxymethylcellulose Pt Complex Chiral Catalyst Asymmetric Hydrogenation Salicyl Alcohol |
| ISSN号 | 1042-7147 |
| 英文摘要 | A new chiral polymer-metal complex, methylsulfosodium carboxymethyl-cellulose-Pt complex (MS-NaCMC-Pt), has been prepared by the reaction of sodium carboxymethylcellulose with methylsulfonyl chloride and H2PtCl6. 6H(2), which was found to he able to catalyze the asymmetric hydrogenation of salicyl alcohol to give (1S,2S)-2-(hydroxymethyl)-cyclohexanol at 28 degrees C and under 1 atm H-2, in > 90% product and optical yields, respectively. The catalyst could be reused many times without any remarkable changes in optical catalytic activity. Copyright (C) 2000 John Wiley & Sons, Ltd. |
| 语种 | 英语 |
| WOS记录号 | WOS:000087653200007 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/76097]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Mao, BW |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Mao, BW,Zhao, AG,Huang, MY,et al. Asymmetric hydrogenation of salicyl alcohol catalyzed by methylsulfo-sodium carboxymethylcellulose-Pt complex[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2000,11(5):250-253. |
| APA | Mao, BW,Zhao, AG,Huang, MY,&Jiang, YY.(2000).Asymmetric hydrogenation of salicyl alcohol catalyzed by methylsulfo-sodium carboxymethylcellulose-Pt complex.POLYMERS FOR ADVANCED TECHNOLOGIES,11(5),250-253. |
| MLA | Mao, BW,et al."Asymmetric hydrogenation of salicyl alcohol catalyzed by methylsulfo-sodium carboxymethylcellulose-Pt complex".POLYMERS FOR ADVANCED TECHNOLOGIES 11.5(2000):250-253. |
入库方式： OAI收割
来源：化学研究所
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