Synthesis and characterization of novel reactive ladder-like polysilsesquioxanes with side-chain ester groups (Ester-Ts)
文献类型：期刊论文
| 作者 | Liu, CQ; Liu, ZH; Xie, P; Dai, DR; Zhang, RB |
| 刊名 | POLYMER INTERNATIONAL
 |
| 出版日期 | 2000-06-01 |
| 卷号 | 49期号:6页码:509-513 |
| 关键词 | Structure-ordered Ladder-like Polysilsesquioxane Stepwise Coupling Polymerization Hydrosilylation Characterization |
| ISSN号 | 0959-8103 |
| 英文摘要 | Two kinds of structure-ordered reactive ladder-like polysilsesquioxanes with different sidechain ester groups (Ester-Ts) have been synthesized successfully by a new route - stepwise coupling polymerization - with three steps including preaminolysis, hydrolysis and polycondensation. Two monomers, 2-trichlorosilylethyl acetate (M-1) and 3-trichlorosilylpropyl propionate (Mz), were first synthesized by hydrosilylation with dicyclopentadienylplatinmm (II) chloride (Cp2PtCl2) as a catalyst. Monomer and polymer structures were characterized by FTIR, H-1 NMR, C-13 NMR, Si-29 NMR, X-ray diffraction (XRD), differential scanning calorimetry (DSC) and vapour pressure osmometry (VPO). Characterization data indicate that these two polymers have ordered ladder-like structures. |
| 语种 | 英语 |
| WOS记录号 | WOS:000087418800005 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/76117]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, RB |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Polymer Chem Lab, Beijing 100080, Peoples R China 2.China Petrochem Corp, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, CQ,Liu, ZH,Xie, P,et al. Synthesis and characterization of novel reactive ladder-like polysilsesquioxanes with side-chain ester groups (Ester-Ts)[J]. POLYMER INTERNATIONAL,2000,49(6):509-513. |
| APA | Liu, CQ,Liu, ZH,Xie, P,Dai, DR,&Zhang, RB.(2000).Synthesis and characterization of novel reactive ladder-like polysilsesquioxanes with side-chain ester groups (Ester-Ts).POLYMER INTERNATIONAL,49(6),509-513. |
| MLA | Liu, CQ,et al."Synthesis and characterization of novel reactive ladder-like polysilsesquioxanes with side-chain ester groups (Ester-Ts)".POLYMER INTERNATIONAL 49.6(2000):509-513. |
入库方式： OAI收割
来源：化学研究所
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