Synthesis and characterization of polystyrene-b-poly(ethylene oxide)-b-polystyrene triblock copolymers by atom-transfer radical polymerization
文献类型：期刊论文
| 作者 | Cheng, SY; Xu, ZS; Yuan, JJ; Ji, PJ; Xu, J; Ye, ML; Shi, LH |
| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
 |
| 出版日期 | 2000-09-23 |
| 卷号 | 77期号:13页码:2882-2888 |
| 关键词 | Ps-b-peo-b-ps Triblock Copolymer Atom-transfer Radical Polymerization Characterization Removal Of Catalysts |
| ISSN号 | 0021-8995 |
| 英文摘要 | Well-defined polystyrene (PS)-b-poly(ethylene oxide) (PEO)-b-PS triblock copolymers were synthesized by atom-transfer radical polymerization (ATRP), using C-X-end-group PEO as macroinitiators. The triblock copolymers were characterized by infrared spectroscopy, nuclear magnetic resonance spectroscopy, and gel permeation chromatography. The experimental results showed that the polymerization was controlled/living. It was found that when the number-average molecular weight of the macroinititors increased from 2000 to 10,000, the molecular weight distribution of the triblock copolymers decreased roughly from 1.49 to 1.07 and the rate of polymerization became much slower. The possible polymerization mechanism is discussed. According to the Cu content measured with atomic absorption spectrometry, the removal of catalysts, with CHCl3 as the solvent and kaolin as the in situ absorption agent, was effective. (C) 2000 John Wiley & Sons, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000088171200010 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/76155]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Cheng, SY |
| 作者单位 | 1.Hubei Univ, Chem & Mat Sci Coll, Wuhan 430062, Peoples R China 2.Chinese Acad Sci, Inst Chem, Polymer Phys Lab, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cheng, SY,Xu, ZS,Yuan, JJ,et al. Synthesis and characterization of polystyrene-b-poly(ethylene oxide)-b-polystyrene triblock copolymers by atom-transfer radical polymerization[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2000,77(13):2882-2888. |
| APA | Cheng, SY.,Xu, ZS.,Yuan, JJ.,Ji, PJ.,Xu, J.,...&Shi, LH.(2000).Synthesis and characterization of polystyrene-b-poly(ethylene oxide)-b-polystyrene triblock copolymers by atom-transfer radical polymerization.JOURNAL OF APPLIED POLYMER SCIENCE,77(13),2882-2888. |
| MLA | Cheng, SY,et al."Synthesis and characterization of polystyrene-b-poly(ethylene oxide)-b-polystyrene triblock copolymers by atom-transfer radical polymerization".JOURNAL OF APPLIED POLYMER SCIENCE 77.13(2000):2882-2888. |
入库方式： OAI收割
来源：化学研究所
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