Synthesis, conformation and metal-binding properties of calix[6]arene derivatives
文献类型：期刊论文
| 作者 | Zhang, WC; Zhu, Y; Li, EC; Liu, TJ; Huang, ZT |
| 刊名 | TETRAHEDRON
 |
| 出版日期 | 2000-05-19 |
| 卷号 | 56期号:21页码:3365-3371 |
| 关键词 | Calix[6]Arene Derivatives 1 1 3 3 5-trimethoxy-2 5-trimethoxy-p-tert-butylcalix[6]Arene 4 6-tribromoethoxycalix[6]Arene |
| ISSN号 | 0040-4020 |
| 英文摘要 | A novel 1,3,5-trimethoxy-2,4,6-tribromoethoxycalix[6]arene (2) as a useful intermediate for the design of new host-guest-type receptors of calix[6]arene with C-3v symmetrical conformation and two 'biscalix[6]arenes' (3-4) has been synthesized by reacting 1,3,5-trimethoxy-p-tert-butylcalix[6]arene (1) with 1,2-dibromoethane in THF in the presence of NaH. Furthermore, several calix[6]arene derivatives 5-7 were then prepared from 2 and their conformational characteristics were studied by dynamic H-1 NMR spectroscopy. The complexing properties toward heavy metal ions of the prepared compound 5 are also reported in this paper with the help of fluorescence spectra and UV-visible spectra. It is shown that this ligand can form relatively stable complexes with Cu2+ and Sn2+. (C) 2000 Elsevier Science Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000087032100010 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/76171]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Huang, ZT |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, WC,Zhu, Y,Li, EC,et al. Synthesis, conformation and metal-binding properties of calix[6]arene derivatives[J]. TETRAHEDRON,2000,56(21):3365-3371. |
| APA | Zhang, WC,Zhu, Y,Li, EC,Liu, TJ,&Huang, ZT.(2000).Synthesis, conformation and metal-binding properties of calix[6]arene derivatives.TETRAHEDRON,56(21),3365-3371. |
| MLA | Zhang, WC,et al."Synthesis, conformation and metal-binding properties of calix[6]arene derivatives".TETRAHEDRON 56.21(2000):3365-3371. |
入库方式： OAI收割
来源：化学研究所
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