Asymmetric hydrogenation of alpha-diketones over polymer-stabilized and supported platinum clusters
文献类型：期刊论文
| 作者 | Zuo, XB; Liu, HF; Tian, JF |
| 刊名 | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
 |
| 出版日期 | 2000-06-20 |
| 卷号 | 157期号:1-2页码:217-224 |
| 关键词 | Alpha-diketone Cinchonidine Platinum Cluster Hydrogenation Enantioselectivity |
| ISSN号 | 1381-1169 |
| 英文摘要 | The asymmetric hydrogenation of alpha-diketones was investigated over finely dispersed polymer-stabilized and supported platinum clusters. It was shown that the rate-accelerating effect of cinchonidine in this reaction was much less pronounced than the case of Pt/cinchona/alpha-ketoester system. The activity and enantiomeric excess (e.e.) for 3-hydroxy-2-butanone reached maximum when the molar ratio of the modifier to reactant was about 1:650. There was no close correlation between the catalytic performance of the platinum clusters and the polarity of the solvents, whereas good enantioselectivity (> 40%) as well as activity could be obtained in a mixture of dichloromethane and ethanol. (C) 2000 Elsevier Science B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000087952600027 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/76285]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, HF |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, PCLCC, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zuo, XB,Liu, HF,Tian, JF. Asymmetric hydrogenation of alpha-diketones over polymer-stabilized and supported platinum clusters[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2000,157(1-2):217-224. |
| APA | Zuo, XB,Liu, HF,&Tian, JF.(2000).Asymmetric hydrogenation of alpha-diketones over polymer-stabilized and supported platinum clusters.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,157(1-2),217-224. |
| MLA | Zuo, XB,et al."Asymmetric hydrogenation of alpha-diketones over polymer-stabilized and supported platinum clusters".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 157.1-2(2000):217-224. |
入库方式： OAI收割
来源：化学研究所
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