Synthesis of decatungstate microporous materials using 1, 10-diaminodecane as template
文献类型：期刊论文
| 作者 | Shao, K; Ma, Y; Chen, ZH; Yao, JN |
| 刊名 | ACTA PHYSICO-CHIMICA SINICA
 |
| 出版日期 | 2000-09-01 |
| 卷号 | 16期号:9页码:769-771 |
| 关键词 | Decatungstate Microporous Materials Templating Synthesis 1 10-diaminodecane |
| ISSN号 | 1000-6818 |
| DOI | 10.3866/PKU.WHXB20000901 |
| 英文摘要 | A novel microporous decatungstate was synthesized by using cationic 1,10-diaminodecane as template under mild chemical conditions. This material was constructed from highly ordered hexagonal array of 1, 10-diaminodecane and decatungstate polyanions. HR-TEM image showed that the decatungstate polyanions "packed" around the 1, 10-diaminodecane molecules. XRD pattern confirmed its hexagonal array (a = b=1.718 nm, c unknown). A template mechanism was proposed to explain its formation process. It is evidenced that 1, 10-diaminodecane molecules play a crucial role in templating the inorganic framework. The cationic diaminodecane molecules "bond" decatungstate polyanions on each end via supermolecular interaction and thus form bolarform structure units. These units pack together and a hexagonal phase is constructed. |
| 语种 | 英语 |
| WOS记录号 | WOS:000089651200001 |
| 出版者 | PEKING UNIV PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/76289]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yao, JN |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shao, K,Ma, Y,Chen, ZH,et al. Synthesis of decatungstate microporous materials using 1, 10-diaminodecane as template[J]. ACTA PHYSICO-CHIMICA SINICA,2000,16(9):769-771. |
| APA | Shao, K,Ma, Y,Chen, ZH,&Yao, JN.(2000).Synthesis of decatungstate microporous materials using 1, 10-diaminodecane as template.ACTA PHYSICO-CHIMICA SINICA,16(9),769-771. |
| MLA | Shao, K,et al."Synthesis of decatungstate microporous materials using 1, 10-diaminodecane as template".ACTA PHYSICO-CHIMICA SINICA 16.9(2000):769-771. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。