Effect of nonionic surfactant additives on the electropolymerization of pyrrole in aqueous solutions
文献类型：期刊论文
| 作者 | Li, YF; Ouyang, JY |
| 刊名 | SYNTHETIC METALS
 |
| 出版日期 | 2000-06-15 |
| 卷号 | 113期号:1-2页码:23-28 |
| 关键词 | Conducting Polymer Polypyrrole Tentile Strength Electropolymerization Nonionic Surfactants |
| ISSN号 | 0379-6779 |
| 英文摘要 | The electrochemical polymerization of pyrrole was performed in the aqueous solutions with and without adding various nonionic surfactants such as nonaphenol polyethyleneoxy (n) ether (OP(n), where n = 4, 7, 10, 15, or 21), octodecyl polyethyleneoxy (20) ether (A-20) and octodecopolyethyleneoxy (10) ester (SE-10) etc. The mechanical properties and surface smoothness of the polypyrrole (PPy) films prepared from the aqueous solutions with addition of the nonionic surfactants OP(n)(n greater than or equal to 7) are greatly improved in comparison with those of the PPy prepared from the aqueous solutions without the surfactants. With the OP(10) additive, the effect of the additive concentration, pH value of the solutions, solution anions, polymerization current and temperature on the mechanical properties of the as-prepared PPy films were studied systematically. Very smooth and flexible PPy film with the tensile strength of 127 MPa and the conductivity of 54 S/cm was obtained from pH 2, 1 mol/l TsONa, 0.1 mol/l pyrrole aqueous solution with the addition of 0.1 mol/l OP(10). (C) 2000 Elsevier Science S.A. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000087539700004 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/76305]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, YF |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Lab Organ Solids, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, YF,Ouyang, JY. Effect of nonionic surfactant additives on the electropolymerization of pyrrole in aqueous solutions[J]. SYNTHETIC METALS,2000,113(1-2):23-28. |
| APA | Li, YF,&Ouyang, JY.(2000).Effect of nonionic surfactant additives on the electropolymerization of pyrrole in aqueous solutions.SYNTHETIC METALS,113(1-2),23-28. |
| MLA | Li, YF,et al."Effect of nonionic surfactant additives on the electropolymerization of pyrrole in aqueous solutions".SYNTHETIC METALS 113.1-2(2000):23-28. |
入库方式： OAI收割
来源：化学研究所
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