Preparation of a methylsulfo-methylcellulose-Pd complex and its catalytic behaviors in asymmetric hydrogenation of o-cresol
文献类型：期刊论文
| 作者 | Mao, BW; Zhao, AG; Huang, MY; Jiang, YY |
| 刊名 | POLYMERS FOR ADVANCED TECHNOLOGIES
 |
| 出版日期 | 2000-05-01 |
| 卷号 | 11期号:5页码:254-257 |
| 关键词 | Methylsulfo-methylcellulose Pd Complex Chiral Catalyst Asymmetric Hydrogenation O-cresol |
| ISSN号 | 1042-7147 |
| 英文摘要 | A new chiral polymer-metal complex, methylsulfomethyl-cellulose-Pd complex (MS-MC-Pd) was prepared by the reaction of methylcellulose with methylsulfonyl chloride, followed by reaction with palladium chloride. The complex obtained was found to catalyze the asymmetric hydrogenation of o-cresol to give (S)-2-methyl-cyclohexanone in more than 90% product and optical yields at 25 degrees C and under 1 atm H-2. The product and optical yields were greatly affected by Pd lending in the complex, solvent quality and reaction temperature. The catalyst could be reused several times without any remarkable loss in optical catalytic activity. Copyright (C) 2000 John Wiley & Sons, Ltd. |
| 语种 | 英语 |
| WOS记录号 | WOS:000087653200008 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/76401]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Mao, BW |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Mao, BW,Zhao, AG,Huang, MY,et al. Preparation of a methylsulfo-methylcellulose-Pd complex and its catalytic behaviors in asymmetric hydrogenation of o-cresol[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2000,11(5):254-257. |
| APA | Mao, BW,Zhao, AG,Huang, MY,&Jiang, YY.(2000).Preparation of a methylsulfo-methylcellulose-Pd complex and its catalytic behaviors in asymmetric hydrogenation of o-cresol.POLYMERS FOR ADVANCED TECHNOLOGIES,11(5),254-257. |
| MLA | Mao, BW,et al."Preparation of a methylsulfo-methylcellulose-Pd complex and its catalytic behaviors in asymmetric hydrogenation of o-cresol".POLYMERS FOR ADVANCED TECHNOLOGIES 11.5(2000):254-257. |
入库方式： OAI收割
来源：化学研究所
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