Transition metal acetylide catalysts for polymerization of polar alkynes
文献类型：期刊论文
| 作者 | Zhan, XW; Yang, MJ; Sun, HM |
| 刊名 | CATALYSIS LETTERS
 |
| 出版日期 | 2000 |
| 卷号 | 70期号:1-2页码:79-82 |
| 关键词 | Polymerization Propargyl Alcohol Poly(Propargyl Alcohol) Transition Metal Acetylide Catalyst |
| ISSN号 | 1011-372X |
| 英文摘要 | A new series of single-component air-stable transition metal acetylide catalysts with the structures ML2(C=CR)(2) (M=Ni and Pd, L=PPh3 and PBu3, R=p-C6H4C=CH, C6H5, H, CH2OH, CH2OCOCH3, CH2OCOC6H5 and CH2OCOC6H4OH-o) for polymerization of polar alkynes were developed. Transition metals, phosphine and alkynyl ligands and solvents exhibited significant influence on the polymerization. Propargyl alcohol could be polymerized with these catalysts under mild conditions to give soluble rich-trans polymers with weight average molecular weights as high as 5.7x10(4) in yields as high as 79%. |
| 语种 | 英语 |
| WOS记录号 | WOS:000165179200013 |
| 出版者 | SPRINGER |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/76445]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yang, MJ |
| 作者单位 | 1.Zhejiang Univ, Dept Polymer Sci & Engn, Hangzhou 310027, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 3.Suzhou Univ, Sch Chem & Chem Engn, Suzhou 215006, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhan, XW,Yang, MJ,Sun, HM. Transition metal acetylide catalysts for polymerization of polar alkynes[J]. CATALYSIS LETTERS,2000,70(1-2):79-82. |
| APA | Zhan, XW,Yang, MJ,&Sun, HM.(2000).Transition metal acetylide catalysts for polymerization of polar alkynes.CATALYSIS LETTERS,70(1-2),79-82. |
| MLA | Zhan, XW,et al."Transition metal acetylide catalysts for polymerization of polar alkynes".CATALYSIS LETTERS 70.1-2(2000):79-82. |
入库方式： OAI收割
来源：化学研究所
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