Synthesis and characterization of ladder-like copolymethyl-epoxysilsesquioxane
文献类型：期刊论文
| 作者 | Cao, M; Li, Z; Zhang, Y; Xie, P; Dai, DR; Zhang, RB; Lin, YH; Chung, NTS |
| 刊名 | REACTIVE & FUNCTIONAL POLYMERS
 |
| 出版日期 | 2000-09-01 |
| 卷号 | 45期号:2页码:119-130 |
| 关键词 | Ladder-like Copolymethyl-epoxysilsesquioxane Hydrosilation |
| ISSN号 | 1381-5148 |
| 英文摘要 | A new kind of copolymethyl-epoxysilsesquioxane (CPMES) was synthesized for the first time by hydrosilation reaction of allyl glycidyl ether (AGE) with the ladder-like polymethylhydrosilsesquioxane (Me-H-T) in the presence of dicyclopentadienylplatinum dichloride (Cp2PtCl2) as catalyst. The graft polymer was characterized by infrared spectroscopy (IR), H-1-NMR. Si-29-NMR, X-ray diffraction (XRD), gel-permeation chromatography (GPC), vapour pressure osmometry (VPO), thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The results indicate that CPMES possesses good solubility in organic solvents, and a greatly improved thermostability compared with polymethyl-epoxysiloxane with a single backbone. (C) 2000 Elsevier Science B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000089549500006 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/76507]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, RB |
| 作者单位 | 1.Chinese Acad Sci, Polymer Chem Lab, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, China Petrochem Corp, Beijing 100080, Peoples R China 3.Natl Univ Singapore, Inst Mat Res & Engn, Singapore, Singapore |
| 推荐引用方式 GB/T 7714 | Cao, M,Li, Z,Zhang, Y,et al. Synthesis and characterization of ladder-like copolymethyl-epoxysilsesquioxane[J]. REACTIVE & FUNCTIONAL POLYMERS,2000,45(2):119-130. |
| APA | Cao, M.,Li, Z.,Zhang, Y.,Xie, P.,Dai, DR.,...&Chung, NTS.(2000).Synthesis and characterization of ladder-like copolymethyl-epoxysilsesquioxane.REACTIVE & FUNCTIONAL POLYMERS,45(2),119-130. |
| MLA | Cao, M,et al."Synthesis and characterization of ladder-like copolymethyl-epoxysilsesquioxane".REACTIVE & FUNCTIONAL POLYMERS 45.2(2000):119-130. |
入库方式： OAI收割
来源：化学研究所
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