Novel network polymer electrolytes based on polysiloxane with internal plasticizer
文献类型：期刊论文
| 作者 | Zhang, ZC; Fang, SB |
| 刊名 | ELECTROCHIMICA ACTA
 |
| 出版日期 | 2000 |
| 卷号 | 45期号:13页码:2131-2138 |
| 关键词 | Network Polymer Electrolytes Internal Plasticizing Chains Hydrosilylation Reaction Ionic Conductivity Vtf Equation |
| ISSN号 | 0013-4686 |
| 英文摘要 | A novel network polymer electrolyte based on the polymethylsiloxane system has been designed and synthesized. In the network polymers, different numbers of PEG chains with various molecular weights were introduced onto the networks as immobile internal plasticizer through a hydrosilylation reaction. The presence of internal plasticizers pendant on the network backbones can lower the glass transition temperatures (T-g) of the electrolytes, make the lithium salt easily dissolved and accelerate the migration of free lithium ions migration. The ambient ionic conductivity (sigma(RT)) was significantly enhanced compared with that of network polymer electrolytes without internal plasticizers. The optimum ionic conductivity was 10(-4.1) S cm(-1) at room temperature and 10(-3.0) S cm(-1) at 80 degrees C. (C) 2000 Elsevier Science Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000086007100011 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/76535]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Fang, SB |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, ZC,Fang, SB. Novel network polymer electrolytes based on polysiloxane with internal plasticizer[J]. ELECTROCHIMICA ACTA,2000,45(13):2131-2138. |
| APA | Zhang, ZC,&Fang, SB.(2000).Novel network polymer electrolytes based on polysiloxane with internal plasticizer.ELECTROCHIMICA ACTA,45(13),2131-2138. |
| MLA | Zhang, ZC,et al."Novel network polymer electrolytes based on polysiloxane with internal plasticizer".ELECTROCHIMICA ACTA 45.13(2000):2131-2138. |
入库方式： OAI收割
来源：化学研究所
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