Molecular arrangement and photochemistry of a bolaamphiphilic anthracene derivative in Langmuir-Blodgett film
文献类型：期刊论文
| 作者 | Lu, Q; Liu, MH |
| 刊名 | JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
 |
| 出版日期 | 2001-11-07 |
| 卷号 | 144期号:2-3页码:159-165 |
| 关键词 | Bolaamphiphile Air/water Interface Monolayer Photodimerization |
| ISSN号 | 1010-6030 |
| 英文摘要 | Molecular arrangement and photochemical reactions have been investigated in the Langmuir-Blodgett (LB) films of a novel bolaamphiphilic anthracene derivative (BISANS) in comparison with those of one-headed amphiphilic anthracene derivative (ANS). It has been found that ANS forms a stable monolayer at the air/water interface, while BISANS undergoes aggregation processes to form crystal film on the water surface, as evidenced from the surface pressure (pi)-area (A) isotherm, scanning electron microscopy (SEM) and X-ray diffraction (XRD) measurements. UV-VIS spectra reveal that both the H-aggregation and the J-aggregation exist in the deposited LB films of bolaamphiphilic BISANS; while only J-aggregation is formed in the LB film of ANS. The content of the H-aggregation in the LB films depends on the transfer surface pressure. The orientation of anthracyl chromophores has an effect on the photoreaction in the LB films. When both the ANS and the BISANS LB films were irradiated with UV light (365 run), photodimerization took place predominantly in nitrogen atmosphere, while photooxidation occurred preferentially in air. (C) 2001 Elsevier Science B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000172314000011 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/76715]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, MH |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Lab Colloid & Interface Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, Q,Liu, MH. Molecular arrangement and photochemistry of a bolaamphiphilic anthracene derivative in Langmuir-Blodgett film[J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,2001,144(2-3):159-165. |
| APA | Lu, Q,&Liu, MH.(2001).Molecular arrangement and photochemistry of a bolaamphiphilic anthracene derivative in Langmuir-Blodgett film.JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY,144(2-3),159-165. |
| MLA | Lu, Q,et al."Molecular arrangement and photochemistry of a bolaamphiphilic anthracene derivative in Langmuir-Blodgett film".JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY 144.2-3(2001):159-165. |
入库方式： OAI收割
来源：化学研究所
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