Preparation of LLDPE using a dual functional catalytic system of Ti(OBu)(4)-Metallocene/B(C6F5)(3)-AlEt3
文献类型：期刊论文
| 作者 | Liu, ZY; Yang, L; Tan, ZJ; He, DW; Hu, YL |
| 刊名 | ACTA POLYMERICA SINICA
 |
| 出版日期 | 2001-08-01 |
| 期号 | 4页码:471-475 |
| 关键词 | Lldpe Dual Functional Catalytic System Zirconocene |
| ISSN号 | 1000-3304 |
| 英文摘要 | Polymeriztion of linear low density polyethylene ( LLDPE) using a dual functional catalytic system containing different kinds of Metallocene /AlEt3/B(C6F5)(3) as copolymerization catalysts and Ti(On-Bu)(4)/AlEt3 as the ethylene dimerization catalyst was studied. Using the single cocatalyst AlEt3 in the catalytic system,it is easy to overcome the shortcoming of interference between two catalytic metals in a single reactor. Among the four zirconocene systems used, the most active dual functional catalytic system is [ Ti(On-Bu)(4)/AlEt3/Et(Ind)(2)ZrCl2/B(C6F5)(3)], its activity reaches 7.5 x 10(6) gPE/molZr(.)h. The density of obtained LLDPE is 0.89 g/cm(3) and 1-butene insertion rate 11.7 mol%. |
| 语种 | 英语 |
| WOS记录号 | WOS:000170584200011 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/76737]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, ZY |
| 作者单位 | 1.Chinese Acad Sci, Ctr Mol Sci, State Key Lab Engn Plast, Beijing 100080, Peoples R China 2.Yanshan Petrochem Co Ltd, Res Inst, Beirut 102500, Lebanon |
| 推荐引用方式 GB/T 7714 | Liu, ZY,Yang, L,Tan, ZJ,et al. Preparation of LLDPE using a dual functional catalytic system of Ti(OBu)(4)-Metallocene/B(C6F5)(3)-AlEt3[J]. ACTA POLYMERICA SINICA,2001(4):471-475. |
| APA | Liu, ZY,Yang, L,Tan, ZJ,He, DW,&Hu, YL.(2001).Preparation of LLDPE using a dual functional catalytic system of Ti(OBu)(4)-Metallocene/B(C6F5)(3)-AlEt3.ACTA POLYMERICA SINICA(4),471-475. |
| MLA | Liu, ZY,et al."Preparation of LLDPE using a dual functional catalytic system of Ti(OBu)(4)-Metallocene/B(C6F5)(3)-AlEt3".ACTA POLYMERICA SINICA .4(2001):471-475. |
入库方式： OAI收割
来源：化学研究所
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