Formation and photodissociation of Chromium/Phosphorus binary clusters
文献类型：期刊论文
| 作者 | Han, CY; Xing, XP; Gao, Z; Zhu, QH |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2001-04-01 |
| 卷号 | 22期号:4页码:622-625 |
| 关键词 | Chromium/phosphorus Clusters Laser Ablation Laser Photodissociation |
| ISSN号 | 0251-0790 |
| 英文摘要 | Chromium/Phosphorus binary clusters were produced by direct laser ablation and analyzed by tandem time-of-flight mass spectrometer. The main clusters formed were rich in phosphorus, There is an oscillation in CrPm+ series(the peaks with even m are stronger than those with odd m, especially the peaks of CrP4+ and CrP8+ are the strongest) and this may be ascribed to the specific stability of P-4 structure. There are some strong peaks such as Cr3P8+, Cr4P9+, Cr5P11+, Cr6P12+, Cr8P14+, etc., which don't change with the change of the ratios of Cr to P in the samples, and their stability could be explained with an electron model of valence electrons filling the d orbitals of Cr, The results of photodissociation just accord with the model. |
| 语种 | 英语 |
| WOS记录号 | WOS:000168362300028 |
| 出版者 | HIGHER EDUCATION PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/76775]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Gao, Z |
| 作者单位 | Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Han, CY,Xing, XP,Gao, Z,et al. Formation and photodissociation of Chromium/Phosphorus binary clusters[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2001,22(4):622-625. |
| APA | Han, CY,Xing, XP,Gao, Z,&Zhu, QH.(2001).Formation and photodissociation of Chromium/Phosphorus binary clusters.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,22(4),622-625. |
| MLA | Han, CY,et al."Formation and photodissociation of Chromium/Phosphorus binary clusters".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 22.4(2001):622-625. |
入库方式： OAI收割
来源：化学研究所
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