Hydrogenation of palm olein catalyzed by polymer stabilized Pt colloids
文献类型：期刊论文
| 作者 | Choo, HP; Liew, KY; Liu, HF; Seng, CE |
| 刊名 | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
 |
| 出版日期 | 2001-01-08 |
| 卷号 | 165期号:1-2页码:127-134 |
| 关键词 | Hydrogenation Palm Olein Pt Nano-cluster Cis-trans Isomerization |
| ISSN号 | 1381-1169 |
| 英文摘要 | Polyvinylpyrolidone stabilized Pt colloids with different polymer: Pt ratios with average particle sizes of between 1.4 and 2.9 nm and narrow size distribution were found to be active for the hydrogenation of palm olein at 35'C and atmospheric pressure. The initial hydrogen consumption rate was high, corresponding to the hydrogenation of the linoleate and slowed down thereafter, corresponding to the oleate hydrogenation. The rate constants for the two competing reactions were determined and the selectivity calculated to be between 10 and 100. The particle size of the Pt clusters influences the rate of the diene much more significantly than the monoene. The smaller the average particle size, the higher is the rate for the diene and hence the higher the selectivity. The trans-isomer formation was comparative low and was found to be a consequence of the partial saturation of the diene rather than the isomerization of the monoene. (C) 2001 Elsevier Science B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000166375300017 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/76793]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liew, KY |
| 作者单位 | 1.Univ Sains Malaysia, Sch Chem Sci, Minden 11800, Penang, Malaysia 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Choo, HP,Liew, KY,Liu, HF,et al. Hydrogenation of palm olein catalyzed by polymer stabilized Pt colloids[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2001,165(1-2):127-134. |
| APA | Choo, HP,Liew, KY,Liu, HF,&Seng, CE.(2001).Hydrogenation of palm olein catalyzed by polymer stabilized Pt colloids.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,165(1-2),127-134. |
| MLA | Choo, HP,et al."Hydrogenation of palm olein catalyzed by polymer stabilized Pt colloids".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 165.1-2(2001):127-134. |
入库方式： OAI收割
来源：化学研究所
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