Synthesis and photochromic property of ethylenediammonium polymolybdate NH3CH2CH2NH3Mo3O10 center dot 4.4H(2)O
文献类型：期刊论文
| 作者 | Shao, K; Ma, Y; Chen, ZH; Zhang, XT; He, T; Yao, JN; Liu, T; Zhang, J; Hu, TD |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 2001 |
| 卷号 | 59期号:8页码:1335-1339 |
| 关键词 | Ethylenediammonium Molybdate Synthesis Photochromic Property |
| ISSN号 | 0567-7351 |
| 英文摘要 | A novel photochromic compound NH3CH2CH2NH3Mo3O10.4.4H(2)O has been synthesized using ethylenediammonium cations as template under mild chemical conditions. Elemental analysis, TGA curve and IR spectra show that its inorganic framework is constructed from infinite chains of (Mo3O10)(infinity)(2-). Ethylenediammonium cations are bounded to the inorganic chain structure through a supramolecular interaction. It is found that this compound has good photochromic property. Differing from vacuum deposited MoO3 film, this compound turns from white to reddish brown after UV irradiation. EXAFS spectra confirm proton transfer from ethylenediammonium cations to Mo-O- after UV irradiation. |
| 语种 | 英语 |
| WOS记录号 | WOS:000170513100030 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/76861]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Shao, K |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst High Energet Phys, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shao, K,Ma, Y,Chen, ZH,et al. Synthesis and photochromic property of ethylenediammonium polymolybdate NH3CH2CH2NH3Mo3O10 center dot 4.4H(2)O[J]. ACTA CHIMICA SINICA,2001,59(8):1335-1339. |
| APA | Shao, K.,Ma, Y.,Chen, ZH.,Zhang, XT.,He, T.,...&Hu, TD.(2001).Synthesis and photochromic property of ethylenediammonium polymolybdate NH3CH2CH2NH3Mo3O10 center dot 4.4H(2)O.ACTA CHIMICA SINICA,59(8),1335-1339. |
| MLA | Shao, K,et al."Synthesis and photochromic property of ethylenediammonium polymolybdate NH3CH2CH2NH3Mo3O10 center dot 4.4H(2)O".ACTA CHIMICA SINICA 59.8(2001):1335-1339. |
入库方式： OAI收割
来源：化学研究所
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