Photoelectron spectroscopic (PES) and theoretical studies on two alkyl nitrites that affect the eco-enviromnent
文献类型：期刊论文
| 作者 | Sun, Z; Zheng, SJ; Wang, DX |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 2001 |
| 卷号 | 59期号:11页码:2031-2033 |
| 关键词 | Alkyl Nitrite Photoelectron Spectroscopy Ab Initio Ionization Potential Alkyloxy Radicals |
| ISSN号 | 0567-7351 |
| 英文摘要 | The photoelectron spectroscopy (PES) of iso - propyl nitrite (CH3)(2)CHONO and tert - butyl nitrite (CH3)(3)CONO are reported. By combining the PES measurements with theoretical calculations on the compounds, we conclude that the first vertical ionization potential for the two compounds are 10.37 and 10.12 eV, respectively. An unmistakable substituent effect on the ionization potential was observed. Comparison of different calculations shows that the outer valence Green's function (OVGF) method gives quite good results in ionization potentials calculations. It is also pointed out that alkyl nitrites are good source for obtaining ROcircle radicals based on the experimental and theoretical analysis. |
| 语种 | 英语 |
| WOS记录号 | WOS:000173115200035 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/77015]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, Z |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100080, Peoples R China 2.Hebei Teachers Univ, Dept Chem, Shijiazhuang 050091, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Z,Zheng, SJ,Wang, DX. Photoelectron spectroscopic (PES) and theoretical studies on two alkyl nitrites that affect the eco-enviromnent[J]. ACTA CHIMICA SINICA,2001,59(11):2031-2033. |
| APA | Sun, Z,Zheng, SJ,&Wang, DX.(2001).Photoelectron spectroscopic (PES) and theoretical studies on two alkyl nitrites that affect the eco-enviromnent.ACTA CHIMICA SINICA,59(11),2031-2033. |
| MLA | Sun, Z,et al."Photoelectron spectroscopic (PES) and theoretical studies on two alkyl nitrites that affect the eco-enviromnent".ACTA CHIMICA SINICA 59.11(2001):2031-2033. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。