Resolution of optical isomers of alpha-hydroxy-acetones by high resolution gas chromatography on chiral stationary phase
文献类型：期刊论文
| 作者 | Zhang, YQ; Shi, XY; Fu, RN; Zhang, HB; Ling, Y; Zuo, XB; Liu, HF |
| 刊名 | CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
 |
| 出版日期 | 2001-03-01 |
| 卷号 | 29期号:3页码:336-338 |
| 关键词 | High Resolution Gas Chromatography Chiral Stationary Phase 2 Bikis [(2 6-di-o-pentyl-3-o-trifluoroacetyl-beta-cyclodextrin 6-di-o-pentyl-3-o-hex-6-o-enyl)-pentakis (2 6 -di-o-pentyl-3-o-methyl)-beta-cyclodextrin-polysiloxane] |
| ISSN号 | 0253-3820 |
| 英文摘要 | Using the cyclodextrin bonded polysiloxane (bikis[(2,6-di-O-pentyl-3-O-hex-6-O-enyl -di-O-pentyl-3-O-methyl)-beta -cyclodextrm-polysiloxane])) as gas chromatographic stationary phase, a-hydroxy-acetones were separated and the values of the enantiomeric excess(e. e) of 3-hydroxy-2-butanone were determined. the results showed that the high resolution gas chromatography (HRGC) using the chiral gas chromatographic stationary phase could determine the productive rate of the asymmetric hydrogenaton reaction and evaluate the enantoselectivity of the catalyst system. |
| 语种 | 英语 |
| WOS记录号 | WOS:000167761200025 |
| 出版者 | FENXI HUAXUE |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/77035]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Fu, RN |
| 作者单位 | 1.Beijing Inst Technol, Sch Chem Engn & Mat Sci, Beijing 100081, Peoples R China 2.Chinese Acad Sci, Inst Chem, Polymer Chem Lab, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, YQ,Shi, XY,Fu, RN,et al. Resolution of optical isomers of alpha-hydroxy-acetones by high resolution gas chromatography on chiral stationary phase[J]. CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,2001,29(3):336-338. |
| APA | Zhang, YQ.,Shi, XY.,Fu, RN.,Zhang, HB.,Ling, Y.,...&Liu, HF.(2001).Resolution of optical isomers of alpha-hydroxy-acetones by high resolution gas chromatography on chiral stationary phase.CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,29(3),336-338. |
| MLA | Zhang, YQ,et al."Resolution of optical isomers of alpha-hydroxy-acetones by high resolution gas chromatography on chiral stationary phase".CHINESE JOURNAL OF ANALYTICAL CHEMISTRY 29.3(2001):336-338. |
入库方式： OAI收割
来源：化学研究所
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