中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Liquid membrane transport of transition metal ions with calix[4] crowns

文献类型:期刊论文

作者Ma, HM; Wang, ZH; Zheng, QY; Wen, LQ
刊名CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
出版日期2001-08-01
卷号22期号:8页码:1315-1318
关键词Liquid Membrane Transport Calix[4] Crowns Transition Metal Ions Cu2++++
ISSN号0251-0790
英文摘要Selective transport of metal ions across liquid membrane can be achieved by using calixarene derivatives with recognition groups. Four new calix[4] crowns, in this work, were examined for the transport of transition metal ions such as Cu2+, Fe3+, Co2+, Ni2+ and Zn2+. It was found that one of these calix crowns, 25 , 27-dihydroxy-26 , 28-(3' , 6' -dioxa-2' , 7' - dioxooctylene) dioxycalix [4] arene (III), transported efficiently Cu2+. Various factors affecting the transport Of Cu2+ with III were investigated in detail, including source phase and receiving phase' s acidities, carrier concentration, time, temperature, etc.. The mechanism of H+ exchange was suggested for the present system H3O- (liquid membrane)-H2O, and the transport process of Cu2+ was briefly discussed.
语种英语
WOS记录号WOS:000170638100012
出版者HIGHER EDUCATION PRESS
源URL[http://ir.iccas.ac.cn/handle/121111/77051]  
专题中国科学院化学研究所
通讯作者Ma, HM
作者单位Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Ma, HM,Wang, ZH,Zheng, QY,et al. Liquid membrane transport of transition metal ions with calix[4] crowns[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2001,22(8):1315-1318.
APA Ma, HM,Wang, ZH,Zheng, QY,&Wen, LQ.(2001).Liquid membrane transport of transition metal ions with calix[4] crowns.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,22(8),1315-1318.
MLA Ma, HM,et al."Liquid membrane transport of transition metal ions with calix[4] crowns".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 22.8(2001):1315-1318.

入库方式: OAI收割

来源:化学研究所

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