Asymmetric hydroformylation of vinyl acetate catalyzed by zeolite-supported gelatin-Co-Ru complex
文献类型：期刊论文
| 作者 | Zhang, X; Han, B; Huang, MY; Jiang, YY |
| 刊名 | POLYMERS FOR ADVANCED TECHNOLOGIES
 |
| 出版日期 | 2001-11-01 |
| 卷号 | 12期号:11-12页码:693-696 |
| 关键词 | Natural Bio-polymer Gelatin-co-ru Complex Chiral Catalyst Asymmetric Hydroformylation Vinyl Acetate |
| ISSN号 | 1042-7147 |
| 英文摘要 | Zeolite-supported gelatin-cobalt-ruthenium complex (zeo-gelatin-Co-Ru) was prepared by a simple method, first the zeolite and gelatin (chiral natural bio-polymer) were mixed to give zeolite-supported gelatin (zeo-gelatin), then this was used as a polymer ligand to react With CoCl2 (.) 6H(2)O and RuCl3 (.) H2O to form the complex. This complex has been found to catalyze the asymmetric hydroformylation of vinyl acetate to give (R)-2-acetoxy-propanal in 83.4% product yield and 90.9% optical yield. And this catalyst could be reused several times without any considerable change in the optical yield. Copyright (C) 2001 John Wiley Sons, Ltd. |
| 语种 | 英语 |
| WOS记录号 | WOS:000173124400014 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/77077]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, X |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, X,Han, B,Huang, MY,et al. Asymmetric hydroformylation of vinyl acetate catalyzed by zeolite-supported gelatin-Co-Ru complex[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2001,12(11-12):693-696. |
| APA | Zhang, X,Han, B,Huang, MY,&Jiang, YY.(2001).Asymmetric hydroformylation of vinyl acetate catalyzed by zeolite-supported gelatin-Co-Ru complex.POLYMERS FOR ADVANCED TECHNOLOGIES,12(11-12),693-696. |
| MLA | Zhang, X,et al."Asymmetric hydroformylation of vinyl acetate catalyzed by zeolite-supported gelatin-Co-Ru complex".POLYMERS FOR ADVANCED TECHNOLOGIES 12.11-12(2001):693-696. |
入库方式： OAI收割
来源：化学研究所
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