Crystalline morphology in a series of CH3-substituted thermotropic aromatic polyesters with even and odd flexible spacers
文献类型:期刊论文
作者 | Chen, SX; Hu, ZM; Song, WH; Jin, YZ; Qian, RY |
刊名 | CHINESE JOURNAL OF POLYMER SCIENCE
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出版日期 | 2001 |
卷号 | 19期号:1页码:71-78 |
关键词 | Crystalline Morphology Spherulite Even-odd Flexible Spacers Ch3-substituted Thermotropic Aromatic Polyester |
ISSN号 | 0256-7679 |
英文摘要 | Crystalline morphology in a series of CH3-substituted main chain thermotropic aromatic polyesters with even and odd numbered methylene spacers has been studied by polarizing optical microscopy (POM), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). On crystallization from solution evaporation spherulites of radial structure were observed in the polymers with even numbered spacers, but spherulites with concentric rings form in the polymer with odd numbered spacers. Both spherulites have a lamellar structure, which is about 10 nm in thickness. On crystallization from nematic glassy state spherulites can not be grown; lamellar structure was only observed around disclinations in a specimen during crystallization. Ln the case of crystallization from nematic melt two types of spherulites can be observed far the sample with even numbered spacers. For the sample with add numbered spacers spherulites can not be formed, but only irregular crystallites. |
语种 | 英语 |
WOS记录号 | WOS:000166329700012 |
出版者 | SPRINGER-VERLAG BERLIN |
源URL | [http://ir.iccas.ac.cn/handle/121111/77129] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Chen, SX |
作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, SX,Hu, ZM,Song, WH,et al. Crystalline morphology in a series of CH3-substituted thermotropic aromatic polyesters with even and odd flexible spacers[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2001,19(1):71-78. |
APA | Chen, SX,Hu, ZM,Song, WH,Jin, YZ,&Qian, RY.(2001).Crystalline morphology in a series of CH3-substituted thermotropic aromatic polyesters with even and odd flexible spacers.CHINESE JOURNAL OF POLYMER SCIENCE,19(1),71-78. |
MLA | Chen, SX,et al."Crystalline morphology in a series of CH3-substituted thermotropic aromatic polyesters with even and odd flexible spacers".CHINESE JOURNAL OF POLYMER SCIENCE 19.1(2001):71-78. |
入库方式: OAI收割
来源:化学研究所
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