Preparation of a new ladderlike oligosilsesquioxane with lateral aryl ester group
文献类型：期刊论文
| 作者 | Ji, SX; Xu, H; Zhou, XS; Dai, DR; Zhang, RB |
| 刊名 | REACTIVE & FUNCTIONAL POLYMERS
 |
| 出版日期 | 2001 |
| 卷号 | 50期号:1页码:23-31 |
| 关键词 | Oligosilsesquioxane Stepwise Coupling Polymerization Hydrosilylation Ladderlike Lateral |
| ISSN号 | 1381-5148 |
| 英文摘要 | A new soluble ladder-like polysilsesquioxane with polar lateral aryl ester group, which has good adhesion properties and could be potential precursors of advanced functional materials such as catalyst carriers, polymeric solid electrolytes and microelectronic packaging materials etc., was successfully synthesized by stepwise coupling polymerization (SCP) method. The monomer used, methyl 4-trichlorosilylpropoxybenzoate, was synthesized by hydrosilylation reaction catalyzed by dicyclopentadienylplatinum(II) dichloride (Cp2PtCl2). The titled polymer was characterized by H-1 NMR, Si-29 NMR, FTIR, X-ray diffraction (XRD) and gel permeation chromatography (GPC). The characterization data demonstrate that the polymer possesses a typical ladder-like structure. (C) 2001 Published by Elsevier Science B.V. |
| 语种 | 英语 |
| WOS记录号 | WOS:000172226500003 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/77131]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Dai, DR |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ji, SX,Xu, H,Zhou, XS,et al. Preparation of a new ladderlike oligosilsesquioxane with lateral aryl ester group[J]. REACTIVE & FUNCTIONAL POLYMERS,2001,50(1):23-31. |
| APA | Ji, SX,Xu, H,Zhou, XS,Dai, DR,&Zhang, RB.(2001).Preparation of a new ladderlike oligosilsesquioxane with lateral aryl ester group.REACTIVE & FUNCTIONAL POLYMERS,50(1),23-31. |
| MLA | Ji, SX,et al."Preparation of a new ladderlike oligosilsesquioxane with lateral aryl ester group".REACTIVE & FUNCTIONAL POLYMERS 50.1(2001):23-31. |
入库方式： OAI收割
来源：化学研究所
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