Preparation of poly (styrene-co-4-vinyl pyridine) /silica nanoscale hybrids supported cyclopentadienyltitanium trichloride (CpTiCl3) catalyst and styrene polymerization
文献类型：期刊论文
| 作者 | Zhu, N; Tang, T; Cui, DM; Feng, ZL; Huang, BT |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2001-12-01 |
| 卷号 | 22期号:12页码:2117-2119 |
| 关键词 | (Stryrene-4-vinylpyridine) Copolymer Organic-inorganic Hybrids Cyclopentadienyltitanium Trichloride Support |
| ISSN号 | 0251-0790 |
| 英文摘要 | To obtain a novel support with practical value for metallocene catalyst (eta -C5H5)TiCl3 (CpTiCl3), poly (styrene-co-4-vinylpyridine) /SiO2 nanoscale hybrid material (SrP/SiO2) was firstly produced as support. After pretreatment by methylaluminoxane (MAO), the hybrid materials reacted with CpTiCl3. The results from SAXS, SEM and TEM indicated the morphology and structure of organic/inorganic hybrid materials, and the size of inorganic particle in hybrid was nanoscale. The results from IR and XPS showed that there were two possible cationic active species in the hybrid-supported catalyst, the polymerization results of styrene proved this possibility. |
| 语种 | 英语 |
| WOS记录号 | WOS:000172815300042 |
| 出版者 | HIGHER EDUCATION PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/77181]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Tang, T |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, Polymer Chem United Lab, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, China Petro Chem Corp, Changchun 130022, Peoples R China 3.NE Univ Technol, Dept Chem, Shenyang 110006, Peoples R China 4.Jilin Inst Technol, Dept Chem Engn, Changchun 130012, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, N,Tang, T,Cui, DM,et al. Preparation of poly (styrene-co-4-vinyl pyridine) /silica nanoscale hybrids supported cyclopentadienyltitanium trichloride (CpTiCl3) catalyst and styrene polymerization[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2001,22(12):2117-2119. |
| APA | Zhu, N,Tang, T,Cui, DM,Feng, ZL,&Huang, BT.(2001).Preparation of poly (styrene-co-4-vinyl pyridine) /silica nanoscale hybrids supported cyclopentadienyltitanium trichloride (CpTiCl3) catalyst and styrene polymerization.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,22(12),2117-2119. |
| MLA | Zhu, N,et al."Preparation of poly (styrene-co-4-vinyl pyridine) /silica nanoscale hybrids supported cyclopentadienyltitanium trichloride (CpTiCl3) catalyst and styrene polymerization".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 22.12(2001):2117-2119. |
入库方式： OAI收割
来源：化学研究所
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