Asymmetric reactions of organosilicon compounds
文献类型：期刊论文
| 作者 | Wang, D |
| 刊名 | CHINESE JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2001-11-01 |
| 卷号 | 21期号:11页码:1090-1094 |
| 关键词 | "carbon Centered" Chiral Organosilicon Compound Hosomi-sakurai Reaction Alpha-silylallyl Carbanion Alkenylsilanol Sharpless Asymmetric Epoxidation |
| ISSN号 | 0253-2786 |
| 英文摘要 | ''Carbon-centered'' chiral organosilicon compounds were synthesized and applied in asymmetric Hosomi-Sakurai reactions and asymmetric reactions of alpha-silylallyl carbanions with aldehydes. Two approaches for improving the stereoselectivities were suggested and examined. The asymmetric epoxidation reactions of alkenylsilanols were carried out, which enlarged the scope of Sharpless asymmetric epoxidation and provided a convenient route to simple optically, active epoxide. |
| 语种 | 英语 |
| WOS记录号 | WOS:000173075900041 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/77187]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, D |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, D. Asymmetric reactions of organosilicon compounds[J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY,2001,21(11):1090-1094. |
| APA | Wang, D.(2001).Asymmetric reactions of organosilicon compounds.CHINESE JOURNAL OF ORGANIC CHEMISTRY,21(11),1090-1094. |
| MLA | Wang, D."Asymmetric reactions of organosilicon compounds".CHINESE JOURNAL OF ORGANIC CHEMISTRY 21.11(2001):1090-1094. |
入库方式： OAI收割
来源：化学研究所
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